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利用波罗蜜果纤维和离子液体制备和表征再生纤维素薄膜。

Preparation and characterization of regenerated cellulose films using borassus fruit fibers and an ionic liquid.

机构信息

Department of Physics, College of Science, Engineering and Technology, University of South Africa, Johannesburg, South Africa.

Department of Chemical Engineering Technology, University of Johannesburg, Johannesburg, South Africa.

出版信息

Carbohydr Polym. 2017 Mar 15;160:203-211. doi: 10.1016/j.carbpol.2016.12.051. Epub 2016 Dec 23.

Abstract

In this study, we successfully extracted cellulose from borassus fruit fibers by chemical process. The extracted cellulose was dissolved in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). Using this solution, regenerated cellulose films were prepared with water as the non solvent. The raw fruit fibers and extracted cellulose were characterized by chemical analysis. The results indicated that the content of the components other than cellulose was significantly decreased during the cellulose extraction process. Further, FTIR, CP-MAS NMR, wide-angle X-ray diffraction (XRD), thermo gravimetric analysis (TGA) and scanning electron microscopy (SEM) were used to provide structural characterization of raw fibers, extracted cellulose and regenerated cellulose films. The average tensile strength, modulus and elongation at break of the regenerated cellulose films were found to be 111±19MPa, 6149±603MPa and 3.1±0.8%, respectively. The notable properties of regenerated cellulose films advocate their effectiveness for various industrial applications.

摘要

在这项研究中,我们通过化学方法成功地从波罗蜜果实纤维中提取了纤维素。提取的纤维素溶解在离子液体 1-烯丙基-3-甲基咪唑氯(AmimCl)中。使用这种溶液,以水作为非溶剂,制备了再生纤维素薄膜。通过化学分析对原果实纤维和提取的纤维素进行了表征。结果表明,在纤维素提取过程中,除纤维素以外的成分含量显著降低。此外,还使用傅里叶变换红外光谱(FTIR)、固态 CP-MAS 核磁共振(CP-MAS NMR)、广角 X 射线衍射(XRD)、热重分析(TGA)和扫描电子显微镜(SEM)对原纤维、提取的纤维素和再生纤维素薄膜进行了结构表征。再生纤维素薄膜的平均拉伸强度、模量和断裂伸长率分别为 111±19MPa、6149±603MPa 和 3.1±0.8%。再生纤维素薄膜的显著性能表明其在各种工业应用中的有效性。

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