Anand V K, Adroja D T, Bhattacharyya A, Klemke B, Lake B
Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner Platz 1, D-14109 Berlin, Germany. ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon, OX11 0QX, United Kingdom.
J Phys Condens Matter. 2017 Apr 5;29(13):135601. doi: 10.1088/1361-648X/aa5b5d. Epub 2017 Jan 31.
The physical properties of an intermetallic compound CeRhGa have been investigated by magnetic susceptibility [Formula: see text], isothermal magnetization M(H), heat capacity [Formula: see text], electrical resistivity [Formula: see text], thermal conductivity [Formula: see text] and thermopower S(T) measurements. CeRhGa is found to crystallize with CaBeGe-type primitive tetragonal structure (space group P4/nmm). No evidence of long range magnetic order is seen down to 1.8 K. The [Formula: see text] data show paramagnetic behavior with an effective moment [Formula: see text]/Ce indicating Ce valence state of Ce ions. The [Formula: see text] data exhibit Kondo lattice behavior with a metallic ground state. The low-T [Formula: see text] data yield an enhanced Sommerfeld coefficient [Formula: see text] mJ/mol K characterizing CeRhGa as a moderate heavy fermion system. The high-T [Formula: see text] and [Formula: see text] show an anomaly near 255 K, reflecting a phase transition. The [Formula: see text] suggests phonon dominated thermal transport with considerably higher values of Lorenz number L(T) compared to the theoretical Sommerfeld value L .
通过磁化率[公式:见正文]、等温磁化强度M(H)、热容[公式:见正文]、电阻率[公式:见正文]、热导率[公式:见正文]和热电势S(T)测量,对金属间化合物CeRhGa的物理性质进行了研究。发现CeRhGa以CaBeGe型原始四方结构(空间群P4/nmm)结晶。在低至1.8 K时未观察到长程磁有序的证据。[公式:见正文]数据显示出顺磁行为,有效磁矩[公式:见正文]/Ce表明Ce离子的Ce价态。[公式:见正文]数据表现出具有金属基态的近藤晶格行为。低温[公式:见正文]数据产生增强的索末菲系数[公式:见正文]mJ/mol K,将CeRhGa表征为中等重费米子系统。高温[公式:见正文]和[公式:见正文]在255 K附近显示出异常,反映了相变。[公式:见正文]表明声子主导热传输,与理论索末菲值L相比,洛伦兹数L(T)的值相当高。