School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China.
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China.
J Colloid Interface Sci. 2017 May 15;494:274-281. doi: 10.1016/j.jcis.2017.01.074. Epub 2017 Feb 2.
In this study, CoO-CeO composite oxide nanotubes (CCONs) have been fabricated by using a simple electrospinning technique followed subsequent annealing and their multifunctional applications for lithium ion batteries and CO oxidation have also been investigated for the first time. When utilized as attractive anodes for lithium-ion batteries (LIBs), the CCONs exhibit good rate capability (497.3mAhg at 2Ag), high initial capacity (826.2mAhg at 0.05Ag) and improved cycling stability (1286.3mAhg after 180 cycles at 0.1Ag and 300.5mAhg with 63.5% retention after 1500 cycles at 1Ag). Furthermore, a preliminary CO catalytic oxidation study has demonstrated that the CCONs samples exhibit high catalytic activity. Thus, these properties endorse CCONs as attractive candidates for both LIBs and CO oxidation and this strategy might open new avenues for the design of a series of transition metal oxides with multicomponent for multifunctional applications.
在这项研究中,我们采用简单的静电纺丝技术制备了 CoO-CeO 复合氧化物纳米管(CCONs),并首次研究了其在锂离子电池和 CO 氧化中的多功能应用。当用作锂离子电池(LIBs)的有吸引力的阳极时,CCONs 表现出良好的倍率性能(在 2Ag 时为 497.3mAhg)、高初始容量(在 0.05Ag 时为 826.2mAhg)和改进的循环稳定性(在 0.1Ag 下 180 次循环后为 1286.3mAhg,在 1Ag 下 1500 次循环后保留 63.5%)。此外,初步的 CO 催化氧化研究表明,CCONs 样品表现出高催化活性。因此,这些特性使 CCONs 成为 LIBs 和 CO 氧化的有吸引力的候选材料,这种策略可能为设计具有多组分的一系列过渡金属氧化物开辟新途径,以实现多功能应用。