• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

利用溶胶-凝胶/碳纳米管修饰电极对六价铬进行高灵敏度检测。

Highly sensitive detection of hexavalent chromium utilizing a sol-gel/carbon nanotube modified electrode.

作者信息

Rosolina Samuel M, Bragg Stefanie A, Ouyang Ruizhuo, Chambers James Q, Xue Zi-Ling

机构信息

Department of Chemistry, University of Tennessee, Knoxville, TN 37996, USA.

出版信息

J Electroanal Chem (Lausanne). 2016 Nov 15;781:120-125. doi: 10.1016/j.jelechem.2016.08.001. Epub 2016 Aug 4.

DOI:10.1016/j.jelechem.2016.08.001
PMID:28167882
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5291338/
Abstract

A pyridine-functionalized thin film has been fabricated to selectively preconcentrate Cr(VI) anions for electrochemical detection in the 5-300 μg L range. Glassy carbon electrodes were modified through physical deposition of single-walled carbon nanotubes (SWNTs) on the electrode surface, followed by electrochemical deposition of a sol-gel containing a 2-pyridine functional group. The use of SWNTs has increased sensitivity for Cr(VI) detection in aqueous solutions, providing a detection limit of 0.8 μg L.

摘要

已制备出一种吡啶功能化薄膜，用于在5 - 300 μg/L范围内选择性预富集Cr(VI)阴离子以进行电化学检测。通过在电极表面物理沉积单壁碳纳米管（SWNTs），然后电化学沉积含有2 - 吡啶官能团的溶胶 - 凝胶，对玻碳电极进行了修饰。SWNTs的使用提高了水溶液中Cr(VI)检测的灵敏度，检测限为0.8 μg/L。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/069cb42502bb/nihms-809856-f0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/3aa9144cffda/nihms-809856-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d33aeab860ad/nihms-809856-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/5ea4c46eef70/nihms-809856-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d8db024f7dc0/nihms-809856-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d10dbb500f56/nihms-809856-f0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/804d9fe9c172/nihms-809856-f0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/6e7ab89bc4bf/nihms-809856-f0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/069cb42502bb/nihms-809856-f0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/3aa9144cffda/nihms-809856-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d33aeab860ad/nihms-809856-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/5ea4c46eef70/nihms-809856-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d8db024f7dc0/nihms-809856-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/d10dbb500f56/nihms-809856-f0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/804d9fe9c172/nihms-809856-f0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/6e7ab89bc4bf/nihms-809856-f0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3d2/5291338/069cb42502bb/nihms-809856-f0009.jpg

相似文献

1
Highly sensitive detection of hexavalent chromium utilizing a sol-gel/carbon nanotube modified electrode.利用溶胶-凝胶/碳纳米管修饰电极对六价铬进行高灵敏度检测。
J Electroanal Chem (Lausanne). 2016 Nov 15;781:120-125. doi: 10.1016/j.jelechem.2016.08.001. Epub 2016 Aug 4.
2
Electrochemical deposition of sol-gel films for enhanced chromium(VI) determination in aqueous solutions.用于增强水溶液中六价铬测定的溶胶-凝胶薄膜的电化学沉积
Anal Chim Acta. 2006 Jul 14;572(1):17-24. doi: 10.1016/j.aca.2006.05.020. Epub 2006 May 16.
3
Improved Bi Film Wrapped Single Walled Carbon Nanotubes for Ultrasensitive Electrochemical Detection of Trace Cr(VI).用于超灵敏电化学检测痕量Cr(VI)的改进型生物膜包裹单壁碳纳米管
Electrochim Acta. 2013 Dec 15;113:686-693. doi: 10.1016/j.electacta.2013.09.110.
4
A novel sensor made of Antimony Doped Tin Oxide-silica composite sol on a glassy carbon electrode modified by single-walled carbon nanotubes for detection of norepinephrine.一种基于掺锑氧化锡-二氧化硅复合溶胶的新型传感器，在经过单壁碳纳米管修饰的玻碳电极上用于检测去甲肾上腺素。
Mater Sci Eng C Mater Biol Appl. 2017 Nov 1;80:180-186. doi: 10.1016/j.msec.2017.03.227. Epub 2017 Mar 25.
5
A highly sensitive and selective electrochemical sensor for determination of Cr(VI) in the presence of Cr(III) using modified multi-walled carbon nanotubes/quercetin screen-printed electrode.采用修饰后的多壁碳纳米管/槲皮素丝网印刷电极，构建了一种高灵敏度、选择性测定 Cr(VI)的电化学传感器，同时实现了 Cr(III)的共存测定。
Mater Sci Eng C Mater Biol Appl. 2013 Dec 1;33(8):4972-7. doi: 10.1016/j.msec.2013.08.020. Epub 2013 Aug 29.
6
Electrochemical Determination of Chromium(VI) in River Water with Gold Nanoparticles-Graphene Nanocomposites Modified Electrodes.基于金纳米粒子-石墨烯纳米复合材料修饰电极的河水中六价铬的电化学测定
Anal Sci. 2018;34(2):155-160. doi: 10.2116/analsci.34.155.
7
Multi-walled carbon nanotubes as adsorbents for the removal of parts per billion levels of hexavalent chromium from aqueous solution.多壁碳纳米管作为吸附剂用于去除水溶液中十亿分之一级别的六价铬。
J Hazard Mater. 2009 Jul 30;166(2-3):1067-75. doi: 10.1016/j.jhazmat.2008.12.011. Epub 2008 Dec 6.
8
Electrochemical determination of nitroaromatic explosives using glassy carbon/multi walled carbon nanotube/polyethyleneimine electrode coated with gold nanoparticles.基于金纳米粒子修饰玻碳/多壁碳纳米管/聚乙烯亚胺电极的电化学法测定硝基芳香族爆炸物。
Talanta. 2022 Feb 1;238(Pt 1):122990. doi: 10.1016/j.talanta.2021.122990. Epub 2021 Oct 22.
9
Electrochemical determination of L-phenylalanine at polyaniline modified carbon electrode based on β-cyclodextrin incorporated carbon nanotube composite material and imprinted sol-gel film.基于β-环糊精包合碳纳米管复合材料和印迹溶胶-凝胶膜的聚苯胺修饰碳电极电化学测定 L-苯丙氨酸
Talanta. 2011 Apr 15;84(2):305-13. doi: 10.1016/j.talanta.2011.01.010. Epub 2011 Jan 15.
10
Sensitive detection of trifluoperazine using a poly-ABSA/SWNTs film-modified glassy carbon electrode.使用聚-ABSA/单壁碳纳米管薄膜修饰玻碳电极灵敏检测三氟拉嗪
Talanta. 2008 Jan 15;74(4):815-20. doi: 10.1016/j.talanta.2007.07.023. Epub 2007 Jul 31.

引用本文的文献

1
Electrochemical Sensors for Heavy Metal Ion Detection in Aqueous Medium: A Systematic Review.用于水介质中重金属离子检测的电化学传感器：系统综述
ACS Omega. 2024 Jun 5;9(24):25493-25512. doi: 10.1021/acsomega.4c00933. eCollection 2024 Jun 18.
2
Recent Advances in Electrochemical Monitoring of Chromium.电化学监测铬的最新进展
Sensors (Basel). 2020 Sep 9;20(18):5153. doi: 10.3390/s20185153.

本文引用的文献

1
Direct analysis of palladium in active pharmaceutical ingredients by anodic stripping voltammetry.采用阳极溶出伏安法直接分析药物有效成分中的钯。
Anal Chim Acta. 2016 Mar 31;914:47-52. doi: 10.1016/j.aca.2016.02.007. Epub 2016 Feb 21.
2
Carcinogenic Chromium(VI) Compounds Formed by Intracellular Oxidation of Chromium(III) Dietary Supplements by Adipocytes.脂肪细胞内源性氧化三价铬膳食补充剂形成的致癌六价铬化合物。
Angew Chem Int Ed Engl. 2016 Jan 26;55(5):1742-5. doi: 10.1002/anie.201509065. Epub 2015 Dec 22.
3
Direct determination of cadmium and lead in pharmaceutical ingredients using anodic stripping voltammetry in aqueous and DMSO/water solutions.在水相和二甲基亚砜/水溶液中使用阳极溶出伏安法直接测定药物成分中的镉和铅。
Anal Chim Acta. 2015 Sep 17;893:25-33. doi: 10.1016/j.aca.2015.07.010. Epub 2015 Aug 8.
4
Phosphinic acid functionalized carbon nanotubes for sensitive and selective sensing of chromium(VI).膦酸功能化碳纳米管用于灵敏和选择性检测六价铬。
J Hazard Mater. 2014 Aug 15;278:559-65. doi: 10.1016/j.jhazmat.2014.06.043. Epub 2014 Jun 28.
5
Potentiometric chemical sensors from lignin-poly(propylene oxide) copolymers doped by carbon nanotubes.基于碳纳米管掺杂的木质素-聚（环氧丙烷）共聚物的电位型化学传感器。
Analyst. 2013 Jan 21;138(2):501-8. doi: 10.1039/c2an36390a.
6
Flower-like self-assembly of gold nanoparticles for highly sensitive electrochemical detection of chromium(VI).金纳米粒子的花状自组装用于六价铬的高灵敏电化学检测。
Anal Chim Acta. 2012 Apr 13;722:1-7. doi: 10.1016/j.aca.2012.01.032. Epub 2012 Feb 16.
7
Selective Determination of Cr(VI) by a Self-Assembled Monolayer-Based Electrode.基于自组装单分子层电极的铬（VI）选择性测定
Anal Chem. 1997 Mar 1;69(5):894-7. doi: 10.1021/ac9607525.
8
Individual and simultaneous determination of lead, cadmium, and zinc by anodic stripping voltammetry at a bismuth bulk electrode.采用铋块电极阳极溶出伏安法同时、分别测定铅、镉和锌。
Talanta. 2010 Jul 15;82(2):675-80. doi: 10.1016/j.talanta.2010.05.031. Epub 2010 May 20.
9
Comment on electrodeposited silicate films: importance of supporting electrolyte.关于电沉积硅酸盐薄膜的评论：支持电解质的重要性。
Anal Chem. 2009 Apr 15;81(8):3199-200. doi: 10.1021/ac900184h.
10
Catalytic adsorptive stripping determination of trace chromium (VI) at the bismuth film electrode.铋膜电极上催化吸附溶出伏安法测定痕量铬（VI）
Talanta. 2005 Jan 15;65(1):144-8. doi: 10.1016/j.talanta.2004.05.044.