• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

氮化硼纳米管在硝酸中的水解开管

Hydrolytic Unzipping of Boron Nitride Nanotubes in Nitric Acid.

作者信息

Kim Dukeun, Muramatsu Hiroyuki, Kim Yoong Ahm

机构信息

Alan G. MacDiarmid Energy Research Institute, School of Polymer Science and Engineering, Chonnam National University, 77 Yongbong-ro, Gwangju, Buk-gu, 61186, Republic of Korea.

Water Environment and Civil Engineering, Faculty of Engineering, Shinshu University, Wakasato, 4-17-1, Nagano, Japan.

出版信息

Nanoscale Res Lett. 2017 Dec;12(1):94. doi: 10.1186/s11671-017-1877-3. Epub 2017 Feb 7.

DOI:10.1186/s11671-017-1877-3
PMID:28176285
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5296259/
Abstract

Boron nitride nanoribbons (BNNRs) have very attractive electrical and optical properties due to their unique edge states and width-related properties. Herein, for the first time, BNNRs were produced by a simple reflux of boron nitride nanotubes (BNNTs) in nitric acid containing water, which had led to unzipped sidewalls through hydrolysis. Their high reactivity that originated from edges was verified via a strong interaction with methylene blue.

摘要

氮化硼纳米带(BNNRs)因其独特的边缘态和与宽度相关的特性而具有非常吸引人的电学和光学性质。在此,首次通过将氮化硼纳米管(BNNTs)在含水硝酸中简单回流制备出了BNNRs,这通过水解导致了侧壁的打开。通过与亚甲基蓝的强相互作用验证了其源自边缘的高反应活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/b9a5f407b32b/11671_2017_1877_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/baeb4e5b3f16/11671_2017_1877_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/84074c383d85/11671_2017_1877_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/aeaa89eac94b/11671_2017_1877_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/b9a5f407b32b/11671_2017_1877_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/baeb4e5b3f16/11671_2017_1877_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/84074c383d85/11671_2017_1877_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/aeaa89eac94b/11671_2017_1877_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f4b8/5296259/b9a5f407b32b/11671_2017_1877_Fig4_HTML.jpg

相似文献

1
Hydrolytic Unzipping of Boron Nitride Nanotubes in Nitric Acid.氮化硼纳米管在硝酸中的水解开管
Nanoscale Res Lett. 2017 Dec;12(1):94. doi: 10.1186/s11671-017-1877-3. Epub 2017 Feb 7.
2
High-yield synthesis of boron nitride nanoribbons via longitudinal splitting of boron nitride nanotubes by potassium vapor.通过钾蒸汽对氮化硼纳米管进行纵向分裂,实现了氮化硼纳米带的高产合成。
ACS Nano. 2014 Oct 28;8(10):9867-73. doi: 10.1021/nn504809n. Epub 2014 Sep 22.
3
Longitudinal splitting of boron nitride nanotubes for the facile synthesis of high quality boron nitride nanoribbons.氮化硼纳米管的纵向劈裂用于高质量氮化硼纳米带的简便合成。
Nano Lett. 2011 Aug 10;11(8):3221-6. doi: 10.1021/nl2014857. Epub 2011 May 24.
4
Dynamical aspects of the unzipping of multiwalled boron nitride nanotubes.多壁氮化硼纳米管解旋的动力学研究
Phys Chem Chem Phys. 2013 Nov 28;15(44):19147-50. doi: 10.1039/c3cp52701h.
5
Sonication-assisted alcoholysis of boron nitride nanotubes for their sidewalls chemical peeling.用于氮化硼纳米管侧壁化学剥离的超声辅助醇解
Chem Commun (Camb). 2015 Apr 28;51(33):7104-7. doi: 10.1039/c5cc00388a.
6
Reactivity of Atomically Functionalized C-Doped Boron Nitride Nanoribbons and Their Interaction with Organosulfur Compounds.原子功能化碳掺杂氮化硼纳米带的反应活性及其与有机硫化合物的相互作用。
Nanomaterials (Basel). 2019 Mar 18;9(3):452. doi: 10.3390/nano9030452.
7
Energy gaps and stark effect in boron nitride nanoribbons.氮化硼纳米带中的能隙与斯塔克效应。
Nano Lett. 2008 Aug;8(8):2200-3. doi: 10.1021/nl080695i. Epub 2008 Jul 2.
8
Electronic properties of single vacancy defect in boron nitride nanoribbons with edge perturbation.边缘扰动的氮化硼纳米带中单空位缺陷的电子性质。
PLoS One. 2024 Aug 9;19(8):e0305555. doi: 10.1371/journal.pone.0305555. eCollection 2024.
9
Water-Induced Bandgap Engineering in Nanoribbons of Hexagonal Boron Nitride.六方氮化硼纳米带中的水致带隙工程
Adv Mater. 2023 Sep;35(36):e2303198. doi: 10.1002/adma.202303198. Epub 2023 Jul 12.
10
Thermo-mechanical properties of boron nitride nanoribbons: A molecular dynamics simulation study.氮化硼纳米带的热机械性能:分子动力学模拟研究
J Mol Graph Model. 2016 Jul;68:1-13. doi: 10.1016/j.jmgm.2016.05.008. Epub 2016 Jun 2.

本文引用的文献

1
Sonication-assisted alcoholysis of boron nitride nanotubes for their sidewalls chemical peeling.用于氮化硼纳米管侧壁化学剥离的超声辅助醇解
Chem Commun (Camb). 2015 Apr 28;51(33):7104-7. doi: 10.1039/c5cc00388a.
2
Nano boron nitride flatland.氮化硼纳米平坦片。
Chem Soc Rev. 2014 Feb 7;43(3):934-59. doi: 10.1039/c3cs60260e.
3
High-quality boron nitride nanoribbons: unzipping during nanotube synthesis.高质量的氮化硼纳米带:在纳米管合成过程中解链。
Angew Chem Int Ed Engl. 2013 Apr 8;52(15):4212-6. doi: 10.1002/anie.201209597. Epub 2013 Mar 4.
4
Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes.碱活化多壁碳纳米管增强吸附去除水溶液中的甲基橙和亚甲基蓝。
ACS Appl Mater Interfaces. 2012 Nov;4(11):5749-60. doi: 10.1021/am301053m. Epub 2012 Oct 24.
5
Fluorinating hexagonal boron nitride into diamond-like nanofilms with tunable band gap and ferromagnetism.将六方氮化硼氟化制成具有可调带隙和铁磁性的类金刚石纳米薄膜。
J Am Chem Soc. 2011 Sep 21;133(37):14831-8. doi: 10.1021/ja206703x. Epub 2011 Aug 29.
6
Boron nitride nanoribbons become metallic.氮化硼纳米带变成金属。
Nano Lett. 2011 Aug 10;11(8):3267-73. doi: 10.1021/nl201616h. Epub 2011 Jul 20.
7
Longitudinal splitting of boron nitride nanotubes for the facile synthesis of high quality boron nitride nanoribbons.氮化硼纳米管的纵向劈裂用于高质量氮化硼纳米带的简便合成。
Nano Lett. 2011 Aug 10;11(8):3221-6. doi: 10.1021/nl2014857. Epub 2011 May 24.
8
"White graphenes": boron nitride nanoribbons via boron nitride nanotube unwrapping."白石墨烯": 通过氮化硼纳米管解缠制备氮化硼纳米带。
Nano Lett. 2010 Dec 8;10(12):5049-55. doi: 10.1021/nl103251m. Epub 2010 Oct 28.
9
Hydrogenation: a simple approach to realize semiconductor-half-metal-metal transition in boron nitride nanoribbons.氢化:一种实现氮化硼纳米带半导体-半金属-金属转变的简单方法。
J Am Chem Soc. 2010 Feb 10;132(5):1699-705. doi: 10.1021/ja908475v.
10
Novel boron nitride hollow nanoribbons.新型氮化硼空心纳米带
ACS Nano. 2008 Oct 28;2(10):2183-91. doi: 10.1021/nn8004922.