Department of Chemistry and Chemical Engineering, Center for Molecular Catalysts and Applications (BK21 plus program), Inha University, Yonghyun Dong 253, 22212, Republic of Korea.
Nanotechnology. 2017 Mar 17;28(11):115605. doi: 10.1088/1361-6528/aa5cf5.
We describe a novel procedure to fabricate WO@surface-mounted metal-organic framework (SURMOF) hybrid materials by electrodeposition of WO nanoparticles into HKUST-1, also termed Cu(BTC) SURMOFs. These materials have been characterized using x-ray diffraction, time-of-flight secondary ion mass spectrometry, scanning electron microscopy, x-ray photoelectron spectroscopy as well as linear sweep voltammetry. The WO semiconductor/SURMOF heterostructures were further tested as hybrid electrodes in their performance for hydrogen evolution reaction from water.
我们描述了一种通过将 WO 纳米粒子电沉积到 HKUST-1（也称为 Cu(BTC) SURMOF）中来制备 WO@表面安装金属有机骨架（SURMOF）杂化材料的新方法。这些材料已经通过 X 射线衍射、飞行时间二次离子质谱、扫描电子显微镜、X 射线光电子能谱以及线性扫描伏安法进行了表征。WO 半导体/SURMOF 异质结构进一步作为混合电极在其从水中析氢反应的性能中进行了测试。
