Pan Rui, Cheng Jian-Wen, Yang Bai-Feng, Yang Guo-Yu
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology , Beijing 100081, China.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
Inorg Chem. 2017 Mar 6;56(5):2371-2374. doi: 10.1021/acs.inorgchem.6b03002. Epub 2017 Feb 20.
The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBGeO (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.
在溶剂热条件下，少量硼原子部分取代四面体位置的锗原子会生成一种新型微孔硼锗酸盐CsBGeO（x = 1）。其骨架结构在已报道的硼锗酸盐中具有最高的锗/硼原子比，并形成了一种新型的方钠石型网络结构。
