• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Ba[GeBO(OH)](OH)(H₂O):Eu及其热转化产物BaGeBO:Eu的发光特性与可控形貌的关系

Luminescence properties in relation to controllable morphologies of Ba[GeBO(OH)](OH)(HO):Eu and its thermal conversion product BaGeBO:Eu.

作者信息

Liang Pan

机构信息

Department of Chemistry & Chemical Engineering, Shaanxi Xueqian Normal University Xi'an 710100 P. R. China

出版信息

RSC Adv. 2019 Jan 8;9(2):891-898. doi: 10.1039/c8ra08636b. eCollection 2019 Jan 2.

DOI:10.1039/c8ra08636b
PMID:35517618
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9059497/
Abstract

Three types of morphologies of Eu-doped BaGeBO(OH)(HO) phosphors were obtained hydrothermal reactions by different kinds of raw materials. In addition, BaGeBO:Eu phosphors were obtained by calcining the precursor BaGeBO(OH)(HO):Eu. The structure and morphology of the obtained samples were characterized by XRD, EDS, FT-IR, TG-DTA, SEM and HRTEM. Herein, the effects of the synthesis parameters, including the reaction temperature, boron sources and the rare earth doping dosage, on the photoluminescence (PL) properties of BaGeBO(OH)(HO) were investigated in detail. The lifetime and absolute quantum yield (QY) of different morphologies of BaGeBO(OH)(HO):Eu were also measured. The PL properties of the BaGeBO:Eu phosphor prepared by the precursor calcination method compared with those prepared by the high-temperature solid-state method are discussed.

摘要

通过使用不同种类的原料进行水热反应，获得了三种形貌的Eu掺杂BaGeBO(OH)(H₂O)荧光粉。此外，通过煅烧前驱体BaGeBO(OH)(H₂O):Eu获得了BaGeBO:Eu荧光粉。采用XRD、EDS、FT-IR、TG-DTA、SEM和HRTEM对所得样品的结构和形貌进行了表征。在此，详细研究了合成参数，包括反应温度、硼源和稀土掺杂量，对BaGeBO(OH)(H₂O)光致发光(PL)性能的影响。还测量了不同形貌的BaGeBO(OH)(H₂O):Eu的寿命和绝对量子产率(QY)。讨论了通过前驱体煅烧法制备的BaGeBO:Eu荧光粉与高温固相法制备的荧光粉的PL性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/ae83ab3559b4/c8ra08636b-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/1126eb859227/c8ra08636b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/028e43a02423/c8ra08636b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/eb97a82d815d/c8ra08636b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/d7eae0471255/c8ra08636b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/4783df19cf49/c8ra08636b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/f11b526d8f70/c8ra08636b-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/add4e1598a44/c8ra08636b-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/10097dc36bb6/c8ra08636b-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/ae83ab3559b4/c8ra08636b-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/1126eb859227/c8ra08636b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/028e43a02423/c8ra08636b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/eb97a82d815d/c8ra08636b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/d7eae0471255/c8ra08636b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/4783df19cf49/c8ra08636b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/f11b526d8f70/c8ra08636b-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/add4e1598a44/c8ra08636b-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/10097dc36bb6/c8ra08636b-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4640/9059497/ae83ab3559b4/c8ra08636b-f9.jpg

相似文献

1
Luminescence properties in relation to controllable morphologies of Ba[GeBO(OH)](OH)(HO):Eu and its thermal conversion product BaGeBO:Eu.Ba[GeBO(OH)](OH)(H₂O):Eu及其热转化产物BaGeBO:Eu的发光特性与可控形貌的关系
RSC Adv. 2019 Jan 8;9(2):891-898. doi: 10.1039/c8ra08636b. eCollection 2019 Jan 2.
2
Hydrothermal synthesis of 4ZnO·BO·HO:Ln (Ln=Eu, Tb) phosphors: Morphology-tunable and luminescence properties.4ZnO·B₂O₃·H₂O:Ln（Ln = Eu、Tb）荧光粉的水热合成：形貌可调性及发光性能
Spectrochim Acta A Mol Biomol Spectrosc. 2018 Feb 5;190:231-238. doi: 10.1016/j.saa.2017.09.040. Epub 2017 Sep 18.
3
Ba3[Ge2B7O16(OH)2](OH)(H2O) and Ba3Ge2B6O16: novel alkaline-earth borogermanates based on two types of polymeric borate units and GeO4 tetrahedra.Ba3[Ge2B7O16(OH)2](OH)(H2O) 和 Ba3Ge2B6O16：基于两种类型聚合硼酸根单元和 GeO4 四面体的新型碱土金属硼锗酸盐。
Inorg Chem. 2011 Apr 4;50(7):3037-43. doi: 10.1021/ic1025697. Epub 2011 Mar 9.
4
Facile and green synthesis of (LaEu)OS red phosphors with sulfate-ion pillared layered hydroxides as a new type of precursor: controlled hydrothermal processing, phase evolution and photoluminescence.以硫酸根离子柱撑层状氢氧化物为新型前驱体简便绿色合成(LaEu)OS红色荧光粉：可控水热过程、相演变及光致发光
Sci Technol Adv Mater. 2013 Dec 20;15(1):014204. doi: 10.1088/1468-6996/15/1/014204. eCollection 2014 Feb.
5
Two- step synthesis and luminescent properties of BaB O :Eu nano/microphosphors prepared from Ba-B-O:Eu precursor.由 Ba-B-O:Eu 前驱体制备的 BaB₂O₄:Eu 纳米/微米荧光粉的两步合成及其发光性能
Luminescence. 2019 Mar;34(2):255-260. doi: 10.1002/bio.3603. Epub 2019 Jan 29.
6
[Study on the Preparation of Ba3Si6O9N4 : Eu(2+) Phosphor and the Characterization of Their Luminescence Properties].[Ba3Si6O9N4:Eu(2+)荧光粉的制备及其发光性能表征研究]
Guang Pu Xue Yu Guang Pu Fen Xi. 2016 Mar;36(3):657-61.
7
Photoluminescence and thermoluminescence properties of Eu doped and Eu ,Dy co-doped Ba MgSi O phosphors.铕掺杂及铕、镝共掺杂的硅酸钡镁荧光粉的光致发光和热释光特性
Luminescence. 2016 Nov;31(7):1364-1371. doi: 10.1002/bio.3116. Epub 2016 Feb 25.
8
Influence of calcination temperature on the luminescent properties of Eu³⁺ doped CaAl₄O₇ phosphor prepared by Pechini method.煅烧温度对采用佩琴尼法制备的 Eu³⁺ 掺杂 CaAl₄O₇ 荧光粉发光性能的影响。
Spectrochim Acta A Mol Biomol Spectrosc. 2015 Jan 5;134:283-7. doi: 10.1016/j.saa.2014.06.023. Epub 2014 Jun 26.
9
Preparation, characterization and luminescence properties of a new hydrous red phosphor CaB O (OH):Eu with different morphologies.一种具有不同形貌的新型含水红色荧光粉CaB₂O₄(OH)₂:Eu的制备、表征及发光性能
Luminescence. 2017 Mar;32(2):217-222. doi: 10.1002/bio.3171. Epub 2016 Jul 12.
10
Enhancing the emission intensity and decreasing the full widths at half maximum of Ba3Si6O12N2:Eu(2+) by Mg(2+) doping.通过Mg(2+)掺杂提高Ba3Si6O12N2:Eu(2+)的发射强度并减小半高宽。
Dalton Trans. 2015 Jun 14;44(22):10321-9. doi: 10.1039/c5dt00815h.

本文引用的文献

1
Centrosymmetric (Hdima)[GeBO(OH)] and Noncentrosymmetric NaGaBO(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate.中心对称的(Hdima)[GeBO(OH)]和非中心对称的NaGaBO(OH)：开放框架硼锗酸盐和硼镓酸盐的溶剂热/表面活性剂热合成
Inorg Chem. 2017 Nov 6;56(21):12695-12698. doi: 10.1021/acs.inorgchem.7b02328.
2
Hydrothermal synthesis of 4ZnO·BO·HO:Ln (Ln=Eu, Tb) phosphors: Morphology-tunable and luminescence properties.4ZnO·B₂O₃·H₂O:Ln（Ln = Eu、Tb）荧光粉的水热合成：形貌可调性及发光性能
Spectrochim Acta A Mol Biomol Spectrosc. 2018 Feb 5;190:231-238. doi: 10.1016/j.saa.2017.09.040. Epub 2017 Sep 18.
3
CsBGeO (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution.
CsBGeO（x = 1）：一种通过部分硼取代具有高Ge/B比的方钠石型硼锗酸盐。
Inorg Chem. 2017 Mar 6;56(5):2371-2374. doi: 10.1021/acs.inorgchem.6b03002. Epub 2017 Feb 20.
4
Synthesis and characterization of the new strontium borogermanate Sr(3-x/2)B(2-x)Ge(4+x)O₁₄ (x = 0.32).新型硼锗酸锶Sr(3 - x/2)B(2 - x)Ge(4 + x)O₁₄（x = 0.32）的合成与表征
Inorg Chem. 2014 Sep 15;53(18):9722-8. doi: 10.1021/ic5012296. Epub 2014 Aug 27.
5
Controllable synthesis of Ln3+ (Ln = Tb, Eu) doped zinc phosphate nano-/micro-structured materials: phase, morphology and luminescence properties.Ln3+（Ln = Tb，Eu）掺杂磷酸锌纳米/微结构材料的可控合成：物相、形貌及发光性能
Nanoscale. 2014 Feb 21;6(4):2137-45. doi: 10.1039/c3nr03749e. Epub 2014 Jan 2.
6
SrGe2B2O8 and Sr3Ge2B6O16: novel strontium borogermanates with three-dimensional and layered anionic architectures.SrGe2B2O8 和 Sr3Ge2B6O16：具有三维和层状阴离子结构的新型硼锗锶酸盐。
Inorg Chem. 2013 Dec 2;52(23):13644-50. doi: 10.1021/ic402214p. Epub 2013 Nov 14.
7
Ba3[Ge2B7O16(OH)2](OH)(H2O) and Ba3Ge2B6O16: novel alkaline-earth borogermanates based on two types of polymeric borate units and GeO4 tetrahedra.Ba3[Ge2B7O16(OH)2](OH)(H2O) 和 Ba3Ge2B6O16：基于两种类型聚合硼酸根单元和 GeO4 四面体的新型碱土金属硼锗酸盐。
Inorg Chem. 2011 Apr 4;50(7):3037-43. doi: 10.1021/ic1025697. Epub 2011 Mar 9.
8
Ln2GeB2O8 (Ln = Nd, Sm-Tb): a series of luminescent lanthanide(III) borogermanates with a layered structure.Ln2GeB2O8 (Ln = Nd, Sm-Tb)：一系列具有层状结构的发光镧系（III）硼锗酸盐。
Dalton Trans. 2010 Jun 14;39(22):5301-5. doi: 10.1039/b927300j. Epub 2010 May 4.