Department of Chemistry, Zhejiang University , Hangzhou 310058, China.
Org Lett. 2017 Mar 3;19(5):969-971. doi: 10.1021/acs.orglett.7b00227. Epub 2017 Feb 21.
A highly Markovnikov-selective, iron-catalyzed hydroboration of styrenes is reported using available oxazolinylphenyl picolinamide as the ligand to afford the branched hydroboration products with up to >50/1 b/l. This reaction is operationally simple and could be carried out in gram scale.
本文报道了一种高 Markovnikov 选择性的铁催化苯乙烯的硼氢化反应，使用易得的恶唑啉基苯基吡啶酰胺作为配体，以高达 >50/1 b/l 的立体选择性得到支化的硼氢化产物。该反应操作简单，可在克级规模下进行。
