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基于木薯淀粉/牛明胶/纳米棒氧化锌的生物纳米复合膜的制备与表征

Preparation and characterization of bionanocomposite film based on tapioca starch/bovine gelatin/nanorod zinc oxide.

作者信息

Marvizadeh Mohammad Mehdi, Oladzadabbasabadi Nazila, Mohammadi Nafchi Abdorreza, Jokar Maryam

机构信息

Young Researchers and Elite Club, Damghan Branch, Islamic Azad University, Damghan, Semnan, Iran.

Department of Chemical Engineering, Shahrood Branch, Islamic Azad University, Shahrood, Iran.

出版信息

Int J Biol Macromol. 2017 Jun;99:1-7. doi: 10.1016/j.ijbiomac.2017.02.067. Epub 2017 Feb 20.

Abstract

To exploring a nano-packaging materials for using as coating or edible films, tapioca starch/gelatin/nanorod ZnO (ZnON) bionanocomposites were prepared via solution casting technique. The effects of nanofiller addition on the mechanical, physicochemical, and crystalline structures, as well as the barrier properties of bionanocomposite films were investigated. X-ray diffraction analysis showed that the bionanocomposite film incorporated with ZnON at a concentration of 3.5% w/w exhibited high intensity peaks compared with control samples. Results of UV-vis spectra analysis showed that incorporation of ZnON into the films can absorb the whole UV light. Tensile strength of the films was increased from 14 to 18MPa whereas elongation at breaks decreased from 18 to 8 percent and oxygen permeability decreased from 151.03 to 91.52cmμm/(m-day) by incorporation of 3.5% ZnON into biopolymer matrix. In summary combined starch/gelatin films supported by ZnON showed better properties compared to starch or gelatin alone. Thus, the bionanocomposite films can be used in food, medicine, and pharmaceutical packaging.

摘要

为探索一种用作涂层或可食用薄膜的纳米包装材料,通过溶液浇铸技术制备了木薯淀粉/明胶/纳米棒氧化锌(ZnON)生物纳米复合材料。研究了添加纳米填料对生物纳米复合薄膜的机械、物理化学和晶体结构以及阻隔性能的影响。X射线衍射分析表明,与对照样品相比,含有3.5%(w/w)ZnON的生物纳米复合薄膜呈现出高强度峰。紫外可见光谱分析结果表明,将ZnON掺入薄膜中可吸收全部紫外光。通过在生物聚合物基质中掺入3.5%的ZnON,薄膜的拉伸强度从14MPa提高到18MPa,而断裂伸长率从18%降低到8%,氧气透过率从151.03cmμm/(m·天)降低到91.52cmμm/(m·天)。总之,与单独的淀粉或明胶相比,由ZnON支撑的淀粉/明胶复合薄膜表现出更好的性能。因此,生物纳米复合薄膜可用于食品、医药和药品包装。

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