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利用单模微波从生物固体中制备生物炭:表征及其除磷潜力。

Biochar produced from biosolids using a single-mode microwave: Characterisation and its potential for phosphorus removal.

作者信息

Antunes Elsa, Schumann James, Brodie Graham, Jacob Mohan V, Schneider Philip A

机构信息

College of Science and Engineering, James Cook University, Townsville, Australia.

College of Science and Engineering, James Cook University, Townsville, Australia; Faculty of Veterinary and Agricultural Sciences, The University of Melbourne, Melbourne, Australia.

出版信息

J Environ Manage. 2017 Jul 1;196:119-126. doi: 10.1016/j.jenvman.2017.02.080. Epub 2017 Mar 9.

Abstract

The amount of biosolids increases every year, and social and environmental concerns are also rising due to heavy metals and pathogen contamination. Even though biosolids are considered as a waste material, they could be used as a precursor in several applications, especially in agriculture due to the presence of essential nutrients. Microwave assisted pyrolysis (MWAP) is a promising technology to safely manage biosolids, while producing value-added products, such as biochar, that can be used to improve soil fertility. This study examined the impact of pyrolysis temperature between 300 °C and 800 °C on the chemical and physical properties of biochar obtained from biosolids via MWAP. Preliminary phosphorus adsorption tests were carried out with the biochar produced from biosolids. This research demonstrated that pyrolysis temperature affects biochar specific surface area, ash and volatiles content, but does not impact heavily on the pH, chemical composition and crystalline phases of the resultant biochar. Biochar yield decreases as the pyrolysis temperature increases. Phosphorus adsorption capacity of biochar was approximately around 15 mg/g of biochar. Biochar resulting from MWAP is a potential candidate for land application with an important role in water and nutrient retention, due to the high surface area.

摘要

生物固体的产量逐年增加,由于重金属和病原体污染,社会和环境方面的担忧也在加剧。尽管生物固体被视为一种废料,但由于其含有必需的养分,它们可以在多种应用中用作前驱体,尤其是在农业领域。微波辅助热解(MWAP)是一种很有前景的技术,可用于安全处理生物固体,同时生产增值产品,如生物炭,可用于提高土壤肥力。本研究考察了300℃至800℃的热解温度对通过MWAP从生物固体中获得的生物炭的化学和物理性质的影响。对生物固体产生的生物炭进行了初步的磷吸附试验。这项研究表明,热解温度会影响生物炭的比表面积、灰分和挥发物含量,但对所得生物炭的pH值、化学成分和晶相影响不大。生物炭产率随热解温度的升高而降低。生物炭的磷吸附容量约为15mg/g生物炭。由于比表面积高,MWAP产生的生物炭是土地应用的潜在候选物,在水和养分保持方面具有重要作用。

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