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MIL-91(Al)晶体结构的重新测定

Re-Determination of the Crystal Structure of MIL-91(Al).

作者信息

Hermer Nele, Wharmby Michael T, Stock Norbert

机构信息

Institute of Inorganic Chemistry Christian-Albrechts-Universität Max-Eyth-Straße 2 24118 Kiel Germany.

Diamond Light Source Ltd. Harwell Science & Innovation Campus OX11 0DE Didcot Oxfordshire UK.

出版信息

Z Anorg Allg Chem. 2017 Jan;643(2):137-140. doi: 10.1002/zaac.201600358. Epub 2016 Dec 16.

DOI:10.1002/zaac.201600358
PMID:28286349
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5324569/
Abstract

The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

摘要

利用高分辨率同步辐射粉末X射线衍射数据，重新测定了首批永久性多孔金属膦酸盐之一MIL-91(Al)的结构。新模型属于较低对称性的空间群，结构中不存在无序配体，不过在其他方面与报道的化合物保持一致。还开发了新的更温和的合成条件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/68e0aa9a9869/ZAAC-643-137-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/a9b723aa96d2/ZAAC-643-137-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/75a9e58e798b/ZAAC-643-137-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/fb5b3448e8ab/ZAAC-643-137-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/68e0aa9a9869/ZAAC-643-137-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/a9b723aa96d2/ZAAC-643-137-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/75a9e58e798b/ZAAC-643-137-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/fb5b3448e8ab/ZAAC-643-137-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2de7/5324569/68e0aa9a9869/ZAAC-643-137-g004.jpg

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本文引用的文献

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