de Oliveira Ricardo Sonsim, Palácio Soraya Moreno, da Silva Edson Antonio, Mariani Filipe Quadros, Reinehr Thiago Olinek
State University of Western Paraná (Unioeste), Toledo, Paraná, Brazil.
Federal Institute of Paraná (IFPR), Cascavel, Paraná, Brazil.
Environ Sci Pollut Res Int. 2017 Apr;24(11):10778-10785. doi: 10.1007/s11356-017-8695-0. Epub 2017 Mar 13.
This study evaluated the feasibility of production of briquettes using fine charcoal, sewage sludge, and mixtures thereof for use in energy production. The briquettes of 7-8 cm diameter and 20 cm length were produced in the conical press extruder type, mixing sewage sludge to charcoal fines in different ratios: 0:100, 25:75, 50:50, 75:25, and 100:0, with the addition of a binder (glue flour) in a ratio of 8 mass% prepared for briquetting. After air drying (temperatures between 24 and 30°C) for 48 h, the mechanical, thermal, and morphological characterizations were performed. The morphological properties of the briquettes were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. The briquettes produced had mechanical strength, with values between 210 and 420 kgf, and densities between 0.75 and 0.91 g cm. The calorific value of briquettes was in the range from 13.21 to 23.10 MJ kg, in which there was an increase with the increase of concentration of charcoal fines in the mixture. Thermogravimetric analysis showed mass losses that occurred in the temperature range between 150 and 740 °C. The results of the mechanical and thermal properties showed the feasibility of using fine charcoal briquettes from sewage sludge as well as mixtures thereof, for the production of energy. The fine charcoal briquette was the one with the highest calorific value, but not showed the highest resistance to mechanical shock.
本研究评估了使用细木炭、污水污泥及其混合物生产用于能源生产的型煤的可行性。采用锥形压块挤出机生产直径7 - 8厘米、长度20厘米的型煤,将污水污泥与细木炭按不同比例混合:0:100、25:75、50:50、75:25和100:0,并添加比例为8质量%的粘结剂(胶粉)用于压块。在24至30°C的温度下空气干燥48小时后,进行机械、热和形态表征。通过扫描电子显微镜(SEM)和傅里叶变换红外(FTIR)光谱对型煤的形态特性进行评估。所生产的型煤具有机械强度,值在210至420千克力之间,密度在0.75至0.91克/立方厘米之间。型煤的热值在13.21至23.10兆焦/千克范围内,其中随着混合物中细木炭浓度的增加而增加。热重分析表明在150至740°C的温度范围内发生了质量损失。机械和热性能结果表明,使用污水污泥细木炭型煤及其混合物用于能源生产是可行的。细木炭型煤具有最高的热值,但未表现出最高的抗机械冲击性。