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一般热力学第三定律的推导和量化。

A general derivation and quantification of the third law of thermodynamics.

机构信息

Department of Physics &Astronomy, University College of London, London WC1E 6BT, UK.

出版信息

Nat Commun. 2017 Mar 14;8:14538. doi: 10.1038/ncomms14538.

DOI:10.1038/ncomms14538
PMID:28290452
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5355879/
Abstract

The most accepted version of the third law of thermodynamics, the unattainability principle, states that any process cannot reach absolute zero temperature in a finite number of steps and within a finite time. Here, we provide a derivation of the principle that applies to arbitrary cooling processes, even those exploiting the laws of quantum mechanics or involving an infinite-dimensional reservoir. We quantify the resources needed to cool a system to any temperature, and translate these resources into the minimal time or number of steps, by considering the notion of a thermal machine that obeys similar restrictions to universal computers. We generally find that the obtainable temperature can scale as an inverse power of the cooling time. Our results also clarify the connection between two versions of the third law (the unattainability principle and the heat theorem), and place ultimate bounds on the speed at which information can be erased.

摘要

热力学第三定律最被广泛接受的版本,即不可达原理,指出任何过程都不能在有限的步骤内和有限的时间内达到绝对零度。在这里,我们提供了一个适用于任意冷却过程的原理推导,即使是那些利用量子力学定律或涉及无限维储层的过程。我们通过考虑类似于通用计算机的热机的概念,量化了将系统冷却到任何温度所需的资源,并将这些资源转化为最小的时间或步骤数。我们通常发现可获得的温度可以按冷却时间的倒数幂缩放。我们的结果还澄清了第三定律的两个版本(不可达原理和热定理)之间的联系,并对信息可以被擦除的速度施加了最终限制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a255/5355879/d44f2d7adf36/ncomms14538-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a255/5355879/324cef2ec674/ncomms14538-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a255/5355879/d44f2d7adf36/ncomms14538-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a255/5355879/324cef2ec674/ncomms14538-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a255/5355879/d44f2d7adf36/ncomms14538-f2.jpg

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Phys Rev E. 2016 Feb;93(2):022126. doi: 10.1103/PhysRevE.93.022126. Epub 2016 Feb 18.
3
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Entropy (Basel). 2023 Oct 10;25(10):1430. doi: 10.3390/e25101430.
4
Controlling the uncontrollable: Quantum control of open-system dynamics.控制不可控之物:开放系统动力学的量子控制
Sci Adv. 2022 Nov 4;8(44):eadd0828. doi: 10.1126/sciadv.add0828. Epub 2022 Nov 2.
5
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Entropy (Basel). 2021 Jun 15;23(6):755. doi: 10.3390/e23060755.
6
The tight Second Law inequality for coherent quantum systems and finite-size heat baths.相干量子系统与有限尺寸热库的严格第二定律不等式。
Nat Commun. 2021 Feb 10;12(1):918. doi: 10.1038/s41467-021-21140-4.
7
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Entropy (Basel). 2018 Feb 12;20(2):122. doi: 10.3390/e20020122.
8
Correlations as a resource in quantum thermodynamics.量子热力学中作为一种资源的关联。
Nat Commun. 2019 Jun 7;10(1):2492. doi: 10.1038/s41467-019-10572-8.
9
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Nat Commun. 2018 Jun 6;9(1):2203. doi: 10.1038/s41467-018-04536-7.
10
Work extraction from quantum systems with bounded fluctuations in work.在有界涨落功的量子系统中提取功。
Nat Commun. 2016 Nov 25;7:13511. doi: 10.1038/ncomms13511.
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4
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