利用非热等离子体引发自由基反应。
Initiating radical reactions with non-thermal plasmas.
作者信息
Gorbanev Yury, Leifert Dirk, Studer Armido, O'Connell Deborah, Chechik Victor
机构信息
Department of Chemistry, University of York, York YO10 5DD, UK.
Organic Chemistry Institute, University of Münster, Corrensstrasse 40, D-48149, Münster, Germany.
出版信息
Chem Commun (Camb). 2017 Mar 28;53(26):3685-3688. doi: 10.1039/c7cc01157a.
Non-thermal plasmas were used as radical initiators in three radical chain reactions: dehalogenation, 5-exo-trig cyclisation and trifluoromethylation with the Togni II reagent. The use of non-volatile solvents (or solvent-free conditions) gave high yields in all reactions under optimised conditions. Short reaction times and mild conditions make this method an attractive alternative to conventional radical initiators.
非热等离子体在三种自由基链式反应中用作自由基引发剂
脱卤反应、5-外向-三取代环化反应以及使用Togni II试剂的三氟甲基化反应。在优化条件下，使用非挥发性溶剂（或无溶剂条件）可使所有反应获得高产率。短反应时间和温和条件使该方法成为传统自由基引发剂的一个有吸引力的替代方法。
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