Department of Chemical and Biochemical Engineering, Technical University of Denmark, DK2800 Kongens Lyngby, Denmark.
Soft Matter. 2017 May 21;13(19):3470-3474. doi: 10.1039/c7sm00126f. Epub 2017 Mar 15.
While fracture in brittle solids has been studied for centuries until today, there are few studies on fracture in polymer liquids. Recent developments in experimental techniques, especially the combination of controlled filament stretching rheometry and high speed imaging, have opened new windows into the detailed study of fracture processes for polymer liquids. High speed imaging shows that polymer liquids fracture like solids with initiation and propagation of an edge fracture. However, remarkable features such as highly reproducible critical stress, independent appearance of multiple fractures, and trumpet crack profiles, reveal mechanisms which are significantly different from solids.
虽然脆性固体的断裂已经研究了几个世纪,但对于聚合物液体的断裂研究却很少。最近实验技术的发展,特别是控制纤维拉伸流变仪和高速成像的结合,为聚合物液体断裂过程的详细研究开辟了新的途径。高速成像表明,聚合物液体的断裂类似于固体,会产生边缘断裂的起始和扩展。然而,一些显著特征,如高度可重复的临界应力、多个断裂的独立出现以及喇叭状裂纹轮廓,揭示了与固体显著不同的机制。