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理性设计的碳纳米点实现纯白光发射。

Rationally Designed Carbon Nanodots towards Pure White-Light Emission.

机构信息

Department of Chemical and Pharmaceutical Sciences, INSTM UdR Trieste, University of Trieste, Via Licio Giorgieri 1, Trieste, 34127, Italy.

Carbon Nanobiotechnology Laboratory CIC biomaGUNE, Paseo de Miramón 182, 20009, Donostia-San Sebastián, Spain.

出版信息

Angew Chem Int Ed Engl. 2017 Apr 3;56(15):4170-4173. doi: 10.1002/anie.201612160. Epub 2017 Mar 13.

Abstract

We report a rational synthesis of carbon nanodots (CNDs) aimed at tailoring their emission, starting from a reasoned choice of organic precursors. To showcase the potential of this approach in a field such as optoelectronics, we designed experiments aimed at preparing materials that emit across the entire visible spectrum. Specifically, using precursors such as arginine, ethylenediamine, naphthalene dianhydride, and 2,6-dibromonaphtalene dianhydride, in appropriate ratios, it was possible to obtain pure white-light (0.33, 0.33; CIE coordinates) emitting carbon nanodots (WCNDs) through a one-step microwave-assisted synthesis and facile purification. The characterization and properties of this novel nanomaterial is discussed.

摘要

我们报告了一种合理合成碳纳米点(CNDs)的方法,旨在通过合理选择有机前体制备发射可调谐的碳纳米点。为了展示这种方法在光电等领域的潜力,我们设计了实验,旨在制备发射整个可见光谱的材料。具体来说,使用精氨酸、乙二胺、萘二酐和 2,6-二溴萘二酐等前体,以适当的比例,通过一步微波辅助合成和简单的纯化,有可能获得纯的白光(0.33,0.33;CIE 坐标)发射碳纳米点(WCNDs)。本文讨论了这种新型纳米材料的特性和性能。

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