Liu Xiao-Jing, Wang Xi, Xu Jia-Li, Tian Dan, Chen Rong-Ying, Xu Jian, Bu Xian-He
School of Materials Science and Engineering, National Institute for Advanced Materials, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300350, P. R. China.
Dalton Trans. 2017 Apr 11;46(15):4893-4897. doi: 10.1039/c7dt00330g.
By means of a mixed-ligand strategy, a novel bi-functional metal-organic framework, [HN(CH)]·Zn(NDC)(atz)·HO (NDC = 2,6-naphthalenedicarboxylic acid, Hatz = 1H-tetrazol-5-amine), was synthesized, which displays a three-dimensional two-fold interpenetrated framework. Owing to the introduction of two different functional organic ligands, this complex exhibits bi-functional properties, i.e., selective gas adsorption of CO over CH and fluorescence sensing response for nitrobenzene.
