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由钴(II)阳离子捕获环-N 阴离子形成的对称 Co(N ) (H O) ⋅4 H O 高氮化合物。

A Symmetric Co(N ) (H O) ⋅4 H O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N Anion.

机构信息

School of Chemical Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu, China.

School of Chemical Engineering, University of Science and Technology Liaoning, Qianshanzhonglu 185, Anshan, Liaoning, China.

出版信息

Angew Chem Int Ed Engl. 2017 Apr 10;56(16):4512-4514. doi: 10.1002/anie.201701070. Epub 2017 Mar 22.

DOI:10.1002/anie.201701070
PMID:28328154
Abstract

The reactions of (N ) (H O) (NH ) Cl with Co(NO ) ⋅6 H O at room temperature yielded Co(N ) (H O) ⋅4 H O as an air-stable orange metal complex. The structure, as determined by single-crystal X-ray diffraction, has two planar cyclo-N rings and four bound water molecules symmetrically positioned around the central metal ion. Thermal analysis demonstrated the explosive properties of the material.

摘要

（N）（HO）（NH）Cl 与 Co（NO）⋅6H2O 在室温下反应，生成了一种稳定的橙色金属配合物 Co（N）（HO）⋅4H2O。通过单晶 X 射线衍射确定的结构具有两个平面环-N 环和四个对称地位于中心金属离子周围的结合水分子。热分析表明该材料具有爆炸性质。

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