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评估萨罗斯湾(位于爱琴海东北部)沿海泻湖中单环芳烃对沉积物的污染。

Evaluation of sediment contamination by monoaromatic hydrocarbons in the coastal lagoons of Gulf of Saros, NE Aegean Sea.

机构信息

Institute of Marine Sciences and Management, Istanbul University, 34134 Vefa, Istanbul, Turkey.

Institute of Marine Sciences and Management, Istanbul University, 34134 Vefa, Istanbul, Turkey.

出版信息

Mar Pollut Bull. 2017 May 15;118(1-2):442-446. doi: 10.1016/j.marpolbul.2017.03.033. Epub 2017 Mar 19.

Abstract

The concentrations and distribution of monoaromatic hydrocarbons (benzene, toluene, ethyl benzene and the sum of m-, p- and o-, xylenes) were determined in the sediments of coastal lagoons of the Gulf of Saros, using a static headspace GC-MS. The total concentrations of BTEX compounds ranged from 368.5 to below detection limit 0.6μgkg dw, with a mean value of 61.5μgkg dw. The light aromatic fraction of m-, p-xylene was the most abundant compound (57.1% in average), and followed by toluene (38.1%)>ethylbenzene (4.1%)>o-xylene (2.5%)>benzene (1.1%). The factor analysis indicated that the levels and distribution of BTEX compounds depend on the type of contaminant source (mobile/point), absorbance of compounds in sediment, and mobility of benzene compound and degradation processes. Point sources are mainly related to agricultural facilities and port activities while the dispersion of compounds are related with their solubility, volatility and effect of sea/saline waters on lagoons.

摘要

采用静态顶空 GC-MS 法测定了萨罗尔湾沿海泻湖沉积物中单芳烃(苯、甲苯、乙苯和间、对、邻二甲苯总和)的浓度和分布。BTEX 化合物的总浓度范围为 368.5 至低于检测限 0.6μgkg dw,平均值为 61.5μgkg dw。m-、p-二甲苯的轻芳烃部分是最丰富的化合物(平均占 57.1%),其次是甲苯(38.1%)>乙苯(4.1%)>邻二甲苯(2.5%)>苯(1.1%)。因子分析表明,BTEX 化合物的水平和分布取决于污染物源的类型(移动/点源)、化合物在沉积物中的吸收、苯化合物的迁移性和降解过程。点源主要与农业设施和港口活动有关,而化合物的分散则与它们的溶解度、挥发性以及海水/盐水对泻湖的影响有关。

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