Lee Tae Hyung, Kim Soo Young, Jang Ho Won
Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 08826, Korea.
School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul 06974, Korea.
Nanomaterials (Basel). 2016 Oct 29;6(11):194. doi: 10.3390/nano6110194.
A century after its first synthesis in 1914, black phosphorus has been attracting significant attention as a promising two-dimensional material in recent years due to its unique properties. Nowadays, with the development of its exfoliation method, there are extensive applications of black phosphorus in transistors, batteries and optoelectronics. Though, because of its hardship in mass production and stability problems, the potential of the black phosphorus in various fields is left unexplored. Here, we provide a comprehensive review of crystal structure, electronic, optical properties and synthesis of black phosphorus. Recent research works about the applications of black phosphorus is summarized. Among them, the possibility of black phosphorous as a solar water splitting photocatalyst is mainly discussed and the feasible novel structure of photocatalysts based on black phosphorous is proposed.
1914年首次合成后的一个世纪里，黑磷近年来因其独特性质作为一种有前景的二维材料受到了广泛关注。如今，随着其剥离方法的发展，黑磷在晶体管、电池和光电子学中有广泛应用。然而，由于其大规模生产困难和稳定性问题，黑磷在各个领域的潜力尚未得到充分探索。在此，我们对黑磷的晶体结构、电子、光学性质及合成进行全面综述。总结了关于黑磷应用的近期研究工作。其中，主要讨论了黑磷作为太阳能光解水催化剂的可能性，并提出了基于黑磷的光催化剂的可行新颖结构。
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