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用于电微电缆的碳纳米管纤维的聚合物涂层

Polymer Coating of Carbon Nanotube Fibers for Electric Microcables.

作者信息

Alvarez Noe T, Ochmann Timothy, Kienzle Nicholas, Ruff Brad, Haase Mark R, Hopkins Tracy, Pixley Sarah, Mast David, Schulz Mark J, Shanov Vesselin

机构信息

Nanoworld Laboratories, University of Cincinnati, Cincinnati, OH 45221, USA.

Chemical and Materials Engineering, University of Cincinnati, Cincinnati, OH 45221, USA.

出版信息

Nanomaterials (Basel). 2014 Nov 4;4(4):879-893. doi: 10.3390/nano4040879.

Abstract

Carbon nanotubes (CNTs) are considered the most promising candidates to replace Cu and Al in a large number of electrical, mechanical and thermal applications. Although most CNT industrial applications require macro and micro size CNT fiber assemblies, several techniques to make conducting CNT fibers, threads, yarns and ropes have been reported to this day, and improvement of their electrical and mechanical conductivity continues. Some electrical applications of these CNT conducting fibers require an insulating layer for electrical insulation and protection against mechanical tearing. Ideally, a flexible insulator such as hydrogenated nitrile butadiene rubber (HNBR) on the CNT fiber can allow fabrication of CNT coils that can be assembled into lightweight, corrosion resistant electrical motors and transformers. HNBR is a largely used commercial polymer that unlike other cable-coating polymers such as polyvinyl chloride (PVC), it provides unique continuous and uniform coating on the CNT fibers. The polymer coated/insulated CNT fibers have a 26.54 μm average diameter-which is approximately four times the diameter of a red blood cell-is produced by a simple dip-coating process. Our results confirm that HNBR in solution creates a few microns uniform insulation and mechanical protection over a CNT fiber that is used as the electrically conducting core.

摘要

碳纳米管(CNTs)被认为是在大量电气、机械和热应用中替代铜和铝的最有前途的候选材料。尽管大多数碳纳米管工业应用需要宏观和微观尺寸的碳纳米管纤维组件,但迄今为止,已经报道了几种制造导电碳纳米管纤维、线、纱和绳索的技术,并且它们的电导率和机械性能仍在不断提高。这些碳纳米管导电纤维的一些电气应用需要绝缘层来进行电绝缘和防止机械撕裂。理想情况下,在碳纳米管纤维上使用诸如氢化丁腈橡胶(HNBR)之类的柔性绝缘体,可以制造出能够组装成轻质、耐腐蚀的电动机和变压器的碳纳米管线圈。HNBR是一种广泛使用的商业聚合物,与其他电缆涂层聚合物(如聚氯乙烯(PVC))不同,它能在碳纳米管纤维上提供独特的连续且均匀的涂层。通过简单的浸涂工艺可生产出聚合物涂覆/绝缘的碳纳米管纤维,其平均直径为26.54μm,约为红细胞直径的四倍。我们的结果证实,溶液中的HNBR会在用作导电芯的碳纳米管纤维上形成几微米厚的均匀绝缘层和机械保护层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63da/5308460/7f352b37703f/nanomaterials-04-00879-g001.jpg

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