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石墨烯和纳米结构碳材料的热性能。

Thermal properties of graphene and nanostructured carbon materials.

机构信息

Department of Electrical Engineering and Materials Science and Engineering Program, Bourns College of Engineering, University of California, Riverside, California 92521, USA.

出版信息

Nat Mater. 2011 Jul 22;10(8):569-81. doi: 10.1038/nmat3064.

DOI:10.1038/nmat3064
PMID:21778997
Abstract

Recent years have seen a rapid growth of interest by the scientific and engineering communities in the thermal properties of materials. Heat removal has become a crucial issue for continuing progress in the electronic industry, and thermal conduction in low-dimensional structures has revealed truly intriguing features. Carbon allotropes and their derivatives occupy a unique place in terms of their ability to conduct heat. The room-temperature thermal conductivity of carbon materials span an extraordinary large range--of over five orders of magnitude--from the lowest in amorphous carbons to the highest in graphene and carbon nanotubes. Here, I review the thermal properties of carbon materials focusing on recent results for graphene, carbon nanotubes and nanostructured carbon materials with different degrees of disorder. Special attention is given to the unusual size dependence of heat conduction in two-dimensional crystals and, specifically, in graphene. I also describe the prospects of applications of graphene and carbon materials for thermal management of electronics.

摘要

近年来,科学界和工程界对材料的热性能产生了浓厚的兴趣。在电子行业不断发展的过程中,散热已经成为一个关键问题,而低维结构中的热传导则呈现出了真正引人入胜的特性。碳的同素异形体及其衍生物在导热方面具有独特的优势。碳材料的室温热导率跨度非常大——超过五个数量级——从非晶碳的最低值到石墨烯和碳纳米管的最高值。在这里,我将重点介绍最近关于石墨烯、碳纳米管和不同无序程度的纳米结构碳材料的研究结果,综述碳材料的热性能。特别关注二维晶体,尤其是石墨烯中热传导的异常尺寸依赖性。我还描述了石墨烯和碳材料在电子设备热管理方面的应用前景。

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本文引用的文献

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Carbon nanotube thermal interface material for high-brightness light-emitting-diode cooling.用于高亮度发光二极管散热的碳纳米管热界面材料。
Nanotechnology. 2008 May 28;19(21):215706. doi: 10.1088/0957-4484/19/21/215706. Epub 2008 Apr 23.
2
A simple molecular mechanics potential for μm scale graphene simulations from the adaptive force matching method.基于自适应力匹配方法的 μm 尺度石墨烯模拟用简单分子力学势。
J Chem Phys. 2011 May 14;134(18):184704. doi: 10.1063/1.3589163.
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Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons.
Sci Adv. 2025 Jul 25;11(30):eadw8588. doi: 10.1126/sciadv.adw8588.
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The Potential of Tellurene-Like Nanosheets as a Solution-Processed Room-Temperature Thermoelectric Material.类碲烯纳米片作为溶液处理室温热电材料的潜力
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Advancing solar energy applications with graphene: the potential of minimally oxidized graphene.利用石墨烯推进太阳能应用:轻度氧化石墨烯的潜力
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Graphene-based wearable biosensors for point-of-care diagnostics: From surface functionalization to biomarker detection.用于即时诊断的基于石墨烯的可穿戴生物传感器:从表面功能化到生物标志物检测。
Mater Today Bio. 2025 Mar 14;32:101667. doi: 10.1016/j.mtbio.2025.101667. eCollection 2025 Jun.
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Robust Laser-Induced Graphene-Boron-Doped Diamond Nanowall Hybrid Nanostructures with Enhanced Field Electron Emission Performance for Microplasma Illumination Devices.用于微等离子体照明装置的具有增强场电子发射性能的稳健激光诱导石墨烯-硼掺杂金刚石纳米壁混合纳米结构。
Small Sci. 2025 Apr 21;5(6):2400430. doi: 10.1002/smsc.202400430. eCollection 2025 Jun.
9
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Nanomaterials (Basel). 2025 May 27;15(11):803. doi: 10.3390/nano15110803.
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Unveiling the microscopic origin of anomalous thermal conductivity in amorphous carbon.揭示非晶碳中反常热导率的微观起源。
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在单层和少层石墨烯中观察到多体效应:二维鞍点激子的观测。
Phys Rev Lett. 2011 Jan 28;106(4):046401. doi: 10.1103/PhysRevLett.106.046401. Epub 2011 Jan 25.
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Thermoelectric power in graphene.石墨烯中的热电势。
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Influence of polymeric residue on the thermal conductivity of suspended bilayer graphene.高分子残留对悬浮双层石墨烯热导率的影响。
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Raman measurements of thermal transport in suspended monolayer graphene of variable sizes in vacuum and gaseous environments.真空中和气体环境中悬浮单层石墨烯的热输运的拉曼测量,其大小可变。
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Thickness-dependent thermal conductivity of encased graphene and ultrathin graphite.封装石墨烯和超薄石墨的厚度相关热导率。
Nano Lett. 2010 Oct 13;10(10):3909-13. doi: 10.1021/nl101613u.
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Dimensional crossover of thermal transport in few-layer graphene.少层石墨烯中热输运的维度穿越。
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