碳纳米管上金纳米粒子的超分子组装：在羟胺催化氧化中的应用。
Supramolecular Assembly of Gold Nanoparticles on Carbon Nanotubes: Application to the Catalytic Oxidation of Hydroxylamines.
作者信息
Shah Nimesh, Basu Pallabita, Prakash Praveen, Donck Simon, Gravel Edmond, Namboothiri Irishi N N, Doris Eric
机构信息
Department of Chemistry, Indian Institute of Technology, Bombay, Mumbai 400076, India.
Alternative Energies and Atomic Energy Commission (CEA), Saclay Institute of Biology and Technology (IBITECS), Department of Bioorganic Chemistry and Isotopic Labeling, 91191 Gif-sur-Yvette, France.
出版信息
Nanomaterials (Basel). 2016 Feb 24;6(3):37. doi: 10.3390/nano6030037.
A supramolecular heterogeneous catalyst was developed by assembly and stabilization of gold nanoparticles on the surface of carbon nanotubes. A layer-by-layer assembly strategy was used and the resulting nanohybrid was involved in the catalytic oxidation of hydroxylamines under mild conditions. The nanohybrid demonstrated high efficiency and selectivity on hydroxylamine substrates.
通过将金纳米颗粒组装并稳定在碳纳米管表面，开发了一种超分子多相催化剂。采用逐层组装策略，所得纳米杂化物参与了温和条件下羟胺的催化氧化反应。该纳米杂化物对羟胺底物表现出高效性和选择性。
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