Jawale Dhanaji V, Gravel Edmond, Boudet Caroline, Shah Nimesh, Geertsen Valérie, Li Haiyan, Namboothiri Irishi N N, Doris Eric
CEA, iBiTecS, Service de Chimie Bioorganique et de Marquage, 91191 Gif-sur-Yvette, France.
Chem Commun (Camb). 2015 Jan 31;51(9):1739-42. doi: 10.1039/c4cc09192b.
Ruthenium nanoparticles were assembled on carbon nanotubes and the resulting nanohybrid was used in the hydrazine-mediated catalytic hydrogenation of various nitroarenes, at room temperature. Depending on the solvent, a selective transformation occurred, giving either access to the corresponding aniline or hydroxylamine derivative.
钌纳米颗粒组装在碳纳米管上,所得纳米杂化物用于在室温下肼介导的各种硝基芳烃的催化氢化反应。根据溶剂的不同,会发生选择性转化,生成相应的苯胺或羟胺衍生物。