Chen Yingzhi, Li Aoxiang, Huang Zheng-Hong, Wang Lu-Ning, Kang Feiyu
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Key Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China.
Nanomaterials (Basel). 2016 Mar 22;6(3):51. doi: 10.3390/nano6030051.
Well-defined organic nanostructures with controllable size and morphology are increasingly exploited in optoelectronic devices. As promising building blocks, porphyrins have demonstrated great potentials in visible-light photocatalytic applications, because of their electrical, optical and catalytic properties. From this perspective, we have summarized the recent significant advances on the design and photocatalytic applications of porphyrin-based nanostructures. The rational strategies, such as texture or crystal modification and interfacial heterostructuring, are described. The applications of the porphyrin-based nanostructures in photocatalytic pollutant degradation and hydrogen evolution are presented. Finally, the ongoing challenges and opportunities for the future development of porphyrin nanostructures in high-quality nanodevices are also proposed.
尺寸和形态可控的明确有机纳米结构在光电器件中的应用越来越广泛。作为有前景的构建模块,卟啉因其电学、光学和催化性质,在可见光光催化应用中展现出了巨大潜力。从这个角度出发,我们总结了基于卟啉的纳米结构在设计和光催化应用方面的近期重要进展。描述了诸如纹理或晶体改性以及界面异质结构等合理策略。介绍了基于卟啉的纳米结构在光催化降解污染物和析氢方面的应用。最后,还提出了卟啉纳米结构在高质量纳米器件未来发展中面临的持续挑战和机遇。