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Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives.

作者信息

Cheval Nicolas, Kampars Valdis, Fowkes Clifford, Shirtcliffe Neil, Fahmi Amir

机构信息

Department of Mechanical, Materials and Manufacturing Engineering, University of Nottingham, Nottingham NG7 2RD, UK.

Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga, LV 1048, Latvia.

出版信息

Nanomaterials (Basel). 2013 Feb 1;3(1):107-116. doi: 10.3390/nano3010107.

DOI:10.3390/nano3010107
PMID:28348324
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5304924/
Abstract

Conductive polymer poly-3-hexylthiophene (P3HT) needles were self-assembled using a second component (indandione derivatives) as a linking agent to enhance their long range alignment. The morphologies of the hybrid organic/organic materials were characterized by transmission electron microscopy (TEM). Both linear and branched structures could be produced, with the degree of branching depending upon the linker used. Incorporation of indandione derivatives broadened the UV absorbance band of P3HT without significant change to its photoluminescence. This hybrid material could open a promising avenue in photovoltaic applications due to its interesting morphologies and optical properties.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/a0c0a6036d8c/nanomaterials-03-00107-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/7ddc23cce124/nanomaterials-03-00107-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/18de9beb6de9/nanomaterials-03-00107-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/5f4e51966cdf/nanomaterials-03-00107-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/1e7e7601f994/nanomaterials-03-00107-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/a0c0a6036d8c/nanomaterials-03-00107-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/7ddc23cce124/nanomaterials-03-00107-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/18de9beb6de9/nanomaterials-03-00107-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/5f4e51966cdf/nanomaterials-03-00107-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/1e7e7601f994/nanomaterials-03-00107-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c047/5304924/a0c0a6036d8c/nanomaterials-03-00107-g005.jpg

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本文引用的文献

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Stepwise Self-Assembly of P3HT/CdSe Hybrid Nanowires with Enhanced Photoconductivity.具有增强光电导率的P3HT/CdSe混合纳米线的逐步自组装
Macromol Rapid Commun. 2009 Aug 18;30(16):1419-23. doi: 10.1002/marc.200900132. Epub 2009 Jun 2.
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Alternative splicing in stem cell self-renewal and diferentiation.干细胞自我更新和分化中的可变剪接。
Adv Exp Med Biol. 2010;695:92-104. doi: 10.1007/978-1-4419-7037-4_7.
3
Molecular dynamics of regioregular poly(3-hexylthiophene) investigated by NMR relaxation and an interpretation of temperature dependent optical absorption.
通过 NMR 弛豫研究规正聚(3-己基噻吩)的分子动力学,并对温度依赖的光吸收进行解释。
J Phys Chem B. 2010 Jan 28;114(3):1241-8. doi: 10.1021/jp910590d.
4
Morphology evolution via self-organization and lateral and vertical diffusion in polymer:fullerene solar cell blends.聚合物:富勒烯太阳能电池共混物中通过自组织以及横向和纵向扩散实现的形态演变
Nat Mater. 2008 Feb;7(2):158-64. doi: 10.1038/nmat2102. Epub 2008 Jan 20.
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Hybrid polymer/zinc oxide photovoltaic devices with vertically oriented ZnO nanorods and an amphiphilic molecular interface layer.具有垂直取向氧化锌纳米棒和两亲性分子界面层的混合聚合物/氧化锌光伏器件。
J Phys Chem B. 2006 Apr 20;110(15):7635-9. doi: 10.1021/jp0571372.