酶促碳正离子环化/重排中固有底物反应性的重要性。
Importance of Inherent Substrate Reactivity in Enzyme-Promoted Carbocation Cyclization/Rearrangements.
机构信息
Department of Chemistry, University of California-Davis, 1 Shields Avenue, Davis, CA, 95616, USA.
出版信息
Angew Chem Int Ed Engl. 2017 Aug 14;56(34):10040-10045. doi: 10.1002/anie.201702363. Epub 2017 Jun 12.
PMID:28349600
Abstract
The importance of inherent substrate reactivity for terpene synthase enzymes is discussed, with a focus on recent experimental tests of predictions derived from computations on gas-phase reactivity of carbocations.
摘要
本文讨论了萜烯合酶中固有底物反应性的重要性，重点介绍了最近对基于气相碳正离子反应性计算的预测进行实验检验的情况。
Zotero 插件