用于高选择性CO捕获的共轭微孔聚三嗪纳米管和纳米球的制备
Fabrication of conjugated microporous polytriazine nanotubes and nanospheres for highly selective CO capture.
作者信息
Wang Zhiqiang, Liu Junling, Fu Yu, Liu Cheng, Pan Chunyue, Liu Zhiyong, Yu Guipeng
机构信息
College of Chemistry and Chemical Engineering, Key Laboratory for Chemical Materials of Xinjiang Uygur Autonomous Region/Engineering Center for Chemical Materials of Xinjiang Corps, Shihezi University, Xinjiang, Shihezi 832003, China.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
出版信息
Chem Commun (Camb). 2017 Apr 6;53(29):4128-4131. doi: 10.1039/c7cc00704c.
A one-spot template approach for fabricating porous organic nanotubes was developed and a molecular design, i.e. introducing thiophene and s-triazine functionalities to enhance host-guest interactions, lead to novel porous solids with high capacities for CO and exceptionally high ideal selectivities over N for effective gas storage and separation.
开发了一种用于制备多孔有机纳米管的单点模板方法，一种分子设计，即引入噻吩和 s-三嗪官能团以增强主客体相互作用，导致了具有高 CO 容量和对 N 具有极高理想选择性的新型多孔固体，用于有效的气体存储和分离。
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