Lead-Based Metal-Organic Framework with Stable Lithium Anodic Performance.
作者信息
Hu Lei, Lin Xiao-Ming, Mo Jun-Ting, Lin Jia, Gan Han-Lin, Yang Xiao-Ling, Cai Yue-Peng
机构信息
Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University , Guangzhou 510006, P. R. China.
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University , Guangzhou 510006, P. R. China.
出版信息
Inorg Chem. 2017 Apr 17;56(8):4289-4295. doi: 10.1021/acs.inorgchem.6b02663. Epub 2017 Mar 30.
A microporous Pb-based metal-organic framework (MOF) [Pb(4,4'-ocppy)]·7HO (Pb-MOF) has been constructed from 4-(4-carboxyphenyl)pyridine N-oxide and Pb(NO). Structural analysis reveals that the Pb-MOF possesses three-dimensional framework with a one-dimensional rhombic channel. When tested as a lithium-ion battery anode, a reversible lithium storage capacity of 489 mAh g was maintained after 500 cycles at 100 mA g as well as excellent cycling stability. The superior electrochemical performance may be derived from the sustenance of the Pb-MOF framework and compositional features of the organic moiety.
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