Mehek Rimsha, Iqbal Naseem, Noor Tayyaba, Amjad M Zain Bin, Ali Ghulam, Vignarooban K, Khan M Abdullah
U.S.-Pakistan Center for Advanced Studies in Energy (USPCAS-E), National University of Sciences and Technology (NUST) H-12 Campus Islamabad 44000 Pakistan
School of Chemical and Materials Engineering (SCME), National University of Sciences and Technology (NUST) Islamabad Pakistan.
RSC Adv. 2021 Sep 1;11(47):29247-29266. doi: 10.1039/d1ra05073g.
Metal-organic frameworks (MOFs) with efficient surface and structural properties have risen as a distinctive class of porous materials through the last few decades, which has enabled MOFs to gain attention in a wide range of applications like drug delivery, gas separation and storage, catalysis and sensors. Likewise, they have also emerged as efficient active materials in energy storage devices owing to their remarkable conducting properties. Metal-organic frameworks (MOFs) have garnered great interest in high-energy-density rechargeable batteries and super-capacitors. Herein the study presents their expanding diversity, structures and chemical compositions which can be tuned at the molecular level. It also aims to evaluate their inherently porous framework and how it facilitates electronic and ionic transportation through the charging and discharging cycles of lithium-ion batteries. In this review we have summarized the various synthesis paths to achieve a particular metal-organic framework. This study focuses mainly on the implementation of metal-organic frameworks as efficient anode and cathode materials for lithium-ion batteries (LIBs) with an evaluation of their influence on cyclic stability and discharge capacity. For this purpose, a brief assessment is made of recent developments in metal-organic frameworks as anode or cathode materials for lithium-ion batteries which would provide enlightenment in optimizing the reaction conditions for designing a MOF structure for the battery community and electrochemical energy storage applications.
在过去几十年中，具有高效表面和结构特性的金属有机框架材料（MOFs）作为一类独特的多孔材料兴起，这使得MOFs在药物递送、气体分离与存储、催化和传感器等广泛应用中受到关注。同样，由于其卓越的导电性能，它们也已成为储能设备中的高效活性材料。金属有机框架材料（MOFs）在高能量密度可充电电池和超级电容器方面引起了极大兴趣。本文介绍了它们不断扩展的多样性、结构和化学成分，这些可以在分子水平上进行调控。它还旨在评估其固有的多孔框架以及该框架如何在锂离子电池的充放电循环中促进电子和离子传输。在这篇综述中，我们总结了实现特定金属有机框架的各种合成路径。本研究主要关注金属有机框架作为锂离子电池（LIBs）高效阳极和阴极材料的应用，并评估它们对循环稳定性和放电容量的影响。为此，对金属有机框架作为锂离子电池阳极或阴极材料的最新进展进行了简要评估，这将为优化反应条件以设计适用于电池领域和电化学储能应用的MOF结构提供启示。
