Department of Civil Engineering & Architecture, University of Pavia, Pavia, 27100, Italy.
Department of Civil Engineering & Architecture, University of Pavia, Pavia, 27100, Italy.
J Environ Manage. 2018 Jun 15;216:176-182. doi: 10.1016/j.jenvman.2017.03.089. Epub 2017 Apr 25.
Disposal of sewage sludge is one of the most important issues in wastewater treatment throughout Europe, as EU sludge production, estimated at 9.5 million tons dry weight in 2005, is expected to approach 13 million tons in 2020. While sludge disposal costs may constitute 30-50% of the total operation costs of wastewater treatment processes, waste sewage sludge still contains resources that may be put to use, like nutrients and energy, that can be recovered through a variety of approaches. Research has shown that waste sewage sludge can be a valuable and very productive feedstock for biodiesel generation, containing lipids (the fats from which biofuels are extracted) in amounts that would require large areas cultivated with typical biodiesel feedstock, to produce, and at a much lower final cost. Several methods have been tested for the production of biodiesel from sewage sludge. To date, among the most efficient such process is pyrolysis, and in particular Microwave-Assisted Pyrolysis (MAP), under which process conditions are more favorable in energetic and economic terms. Sludge characteristics are very variable, depending on the characteristics of the wastewater-generating service area and on the wastewater treatment process itself. Each sludge can be considered a unique case, and as such experimental determination of the optimal biodiesel yields must be conducted on a case-by-case basis. In addition to biodiesel, other pyrolysis products can add to the energetic yield of the process (and not only). This paper discusses how feedstock properties and process characteristics may influence biodiesel (and other products) yield from pyrolytic (and in particular, MAP) processes, and discusses future possible technological developments.
处理污水污泥是整个欧洲废水处理中最重要的问题之一,因为欧盟污泥产量预计将从 2005 年的 950 万吨干重增加到 2020 年的 1300 万吨。尽管污泥处理成本可能占废水处理工艺总成本的 30-50%,但废污水污泥仍然含有可利用的资源,如营养物质和能源,可以通过多种方法回收。研究表明,废污水污泥可以成为生物柴油生产的一种有价值且非常有生产力的原料,其中含有大量的脂质(从生物燃料中提取的脂肪),这些脂质需要用典型的生物柴油原料在大面积种植才能产生,而且最终成本要低得多。已经测试了几种从污水污泥中生产生物柴油的方法。迄今为止,最有效的方法之一是热解,特别是微波辅助热解 (MAP),在这种工艺条件下,在能量和经济方面更有利。污泥特性非常多变,取决于产生废水的服务区的特性和废水处理工艺本身。每一种污泥都可以被认为是一个独特的案例,因此必须根据具体情况进行实验确定最佳的生物柴油产量。除了生物柴油,其他热解产物可以增加工艺的能量产量(不仅仅是)。本文讨论了原料特性和工艺特性如何影响热解(特别是 MAP)过程中的生物柴油(和其他产品)产量,并讨论了未来可能的技术发展。