Liu Ji-Mei, Zhang De-Wu, Du Wen-Yu, Zhang Min, Zhao Jin-Lian, Chen Ri-Dao, Xie Ke-Bo, Dai Jun-Gui
a State Key Laboratory of Bioactive Substance and Function of Natural Medicines , Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College , Beijing 100050 , China.
b Key Laboratory of Biosynthesis of Natural Products of National Health and Family Planning Commission , Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College , Beijing 100050 , China.
J Asian Nat Prod Res. 2017 Jun;19(6):541-549. doi: 10.1080/10286020.2017.1313241. Epub 2017 Apr 11.
Five monoterpenoids were isolated from the endophytic fungus Periconia sp. F-31, including three new carene-type monoterpenoids, 2-carene-5,8-diol (1), 2-carene-8,10-diol (2), 2-carene-8-acetamide (3), one new menthene-type monoterpenoid 8-hydroxy-1,7-expoxy-2-menthene (4), and one known monoterpenoid anethofuran (5). The structures of all compounds were elucidated based on a comprehensive spectroscopic data analysis, electronic circular dichroism (ECD), and calculated ECD.
从内生真菌佩里孔尼亚菌属Periconia sp. F-31中分离出5种单萜类化合物,包括3种新的蒈烯型单萜类化合物,2-蒈烯-5,8-二醇(1)、2-蒈烯-8,10-二醇(2)、2-蒈烯-8-乙酰胺(3),1种新的薄荷烯型单萜类化合物8-羟基-1,7-环氧-2-薄荷烯(4),以及1种已知的单萜类化合物大茴香脑(5)。所有化合物的结构均通过综合光谱数据分析、电子圆二色光谱(ECD)和计算ECD得以阐明。