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三尖杉中的枞酸型二萜类化合物。

Abietane diterpenoids from Cephalotaxus lanceolata.

作者信息

Chen Xiao-Jiao, Ni Ling, Bao Mei-Fen, Wang Li, Cai Xiang-Hai

机构信息

a College of Horticulture and Landscape , Yunnan Agricultural University , Kunming , China.

b State Key Laboratory of Phytochemistry and Plant Resources in West China , Kunming Institute of Botany, Chinese Academy of Sciences , Kunming , China.

出版信息

Nat Prod Res. 2017 Nov;31(21):2473-2478. doi: 10.1080/14786419.2017.1314280. Epub 2017 Apr 12.

Abstract

A new abietane diterpenoid, 12-O-methyl-20-deoxocarnosol-3-one (1), and eight known abietane diterpenoids including 13-abietadien-12-one (2), 5,6-dehydrosugiol (3), sugiol (4), torreyayunnin (5), taxusabietane A (6), hinokiol (7), 3-acetoxyabieta-8,11,13-trien-12-ol (8), and martiusane (9) were obtained from leaves and twigs of Cephalotaxus lanceolata. The structures of isolated compounds (1-9) were determined based on analysis of their spectroscopic data and comparison with those reported in the literature. Compounds 3, 8 and 9 were first isolated from the plants of Cephalotaxus genus.

摘要

从披针叶红豆杉的叶和嫩枝中得到了一种新的枞酸型二萜,12 - O - 甲基 - 20 - 脱氧卡诺醇 - 3 - 酮(1),以及8种已知的枞酸型二萜,包括13 - 枞二烯 - 12 - 酮(2)、5,6 - 脱氢苏乔醇(3)、苏乔醇(4)、南方红豆杉素(5)、紫杉枞烷A(6)、扁柏酚(7)、3 - 乙酰氧基枞 - 8,11,13 - 三烯 - 12 - 醇(8)和马丁烷(9)。通过对分离得到的化合物(1 - 9)的光谱数据进行分析,并与文献报道的数据进行比较,确定了它们的结构。化合物3、8和9首次从红豆杉属植物中分离得到。

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