Yan Leiming, Wu Jisi, Zhang Lei, Liu Xinli, Zhou Kechao, Su Bo
State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, P.R. China.
State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, P.R. China.
Mater Sci Eng C Mater Biol Appl. 2017 Jun 1;75:335-340. doi: 10.1016/j.msec.2016.12.044. Epub 2016 Dec 12.
Porous titanium scaffolds with long-range lamellar structure were fabricated using a novel bidirectional freeze casting method. Compared with the ordinarily porous titanium materials made by traditional freeze casting, the titanium walls can offer the structure of ordered arrays with parallel to each other in the transverse cross-sections. And titanium scaffolds with different pore width, wall size and porosity can be synthesized in terms of adjusting the fabrication parameters. As the titanium content was increased from 15vol.% to 25vol.%, the porosity and pore width decreased from 67±3% to 50±2% and 80±10μm to 67±7μm, respectively. On the contrary, as the wall size was increased from 18±2μm to 30±3μm, the compressive strength and stiffness were increased from 58±8MPa to 162±10MPa and from 2.5±0.7GPa to 6.5±0.9GPa, respectively. The porous titanium scaffolds with long-range lamellar structure and controllable pore structure produced in present work will be capable of having potential application as bone tissue scaffold materials.
采用一种新型双向冷冻铸造法制备了具有长程层状结构的多孔钛支架。与传统冷冻铸造法制备的普通多孔钛材料相比,钛壁在横向截面中可提供相互平行的有序阵列结构。并且可以通过调整制备参数来合成具有不同孔径、壁厚和孔隙率的钛支架。当钛含量从15体积%增加到25体积%时,孔隙率和孔径分别从67±3%降至50±2%,从80±10μm降至67±7μm。相反,当壁厚从18±2μm增加到30±3μm时,抗压强度和刚度分别从58±8MPa增加到162±10MPa,从2.5±0.7GPa增加到6.5±0.9GPa。本研究中制备的具有长程层状结构和可控孔隙结构的多孔钛支架有望作为骨组织支架材料具有潜在应用。