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田间重返作业时暴露于农药的评估:可脱落叶面残留研究。

Assessment of field re-entry exposure to pesticides: A dislodgeable foliar residue study.

机构信息

Laboratory of Pesticides' Toxicology, Benaki Phytopathological Institute, 8 St. Delta Str., Kifissia, 14561 Athens, Greece.

Laboratory of Pesticides' Toxicology, Benaki Phytopathological Institute, 8 St. Delta Str., Kifissia, 14561 Athens, Greece.

出版信息

Sci Total Environ. 2017 Oct 15;596-597:178-186. doi: 10.1016/j.scitotenv.2017.04.016. Epub 2017 Apr 19.

Abstract

A dislodgeable foliar residue study was conducted in greenhouse pepper and tomato on the island of Crete, Greece, following the spray application of an SC insecticide (with active substance (a.s.) tebufenozide) and an EC fungicide (a.s. bupirimate). Furthermore, for the assessment of worker exposure to pesticides - as a result of re-entering the treated crops - a worker dermal exposure study was carried out during the tasks of tying or pruning, which allowed the transfer coefficient values for the specific tasks to be determined. Pesticide residues were analysed with an in house developed and fully validated HPLC-ESI/MS analytical method. The results from the study resulted in transfer coefficient values which were in agreement with current EFSA guideline values in most of the cases with the exception of bupirimate in a tomato greenhouse. In that case, high potential dermal exposure and low dislodgeable foliar residue values were observed, which is thought to be due to the moist leaves collected during sampling and monitoring, which led to greater than expected transfer coefficient values.

摘要

在希腊克里特岛的温室辣椒和番茄上进行了可脱落叶面残留研究,喷雾施用了一种 SC 杀虫剂(有效成分(a.s.)虫酰肼)和一种 EC 杀菌剂(有效成分(a.s.)双丙环虫酯)。此外,为了评估工人因重新进入处理过的作物而接触农药的情况,在系绳或修剪等任务期间进行了工人皮肤接触研究,从而确定了特定任务的转移系数值。使用内部开发并经过充分验证的 HPLC-ESI/MS 分析方法对农药残留进行了分析。研究结果得出的转移系数值与大多数情况下现行的 EFSA 指南值一致,但在番茄温室中的双丙环虫酯除外。在这种情况下,观察到高潜在的皮肤接触和低可脱落叶面残留值,这被认为是由于在采样和监测过程中收集的潮湿叶片导致了大于预期的转移系数值。

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