硼氧六环共价有机框架单层膜的无溶剂表面合成
Solvent-free on-surface synthesis of boroxine COF monolayers.
作者信息
Spitzer Saskia, Rastgoo-Lahrood Atena, Macknapp Klaus, Ritter Viktoria, Sotier Stefan, Heckl Wolfgang M, Lackinger Markus
机构信息
Deutsches Museum, Museumsinsel 1, 80538, Munich, Germany.
出版信息
Chem Commun (Camb). 2017 May 4;53(37):5147-5150. doi: 10.1039/c7cc01131h.
PMID:28435950
Abstract
A protocol is proposed for the solvent-free on-surface synthesis of covalent organic framework monolayers by condensation of diboronic acids. Monomers are vapor-deposited and water is used for equilibrium regulation. Samples are characterized on progressively smaller length scales by light microscopy, Scanning Electron Microscopy, and Scanning Tunneling Microscopy.
摘要
提出了一种通过二硼酸缩合在表面无溶剂合成共价有机框架单层的方案。单体通过气相沉积，水用于平衡调节。通过光学显微镜、扫描电子显微镜和扫描隧道显微镜在逐渐减小的长度尺度上对样品进行表征。
Zotero 插件