烯烃的分子内 Minisci 反应的氢化吡啶化。
Hydropyridylation of Olefins by Intramolecular Minisci Reaction.
机构信息
School of Science and Technology, Chemistry Division, University of Camerino , via S. Agostino 1, I-62032 Camerino (MC), Italy.
出版信息
Org Lett. 2017 May 5;19(9):2290-2293. doi: 10.1021/acs.orglett.7b00833. Epub 2017 Apr 25.
PMID:28440081
Abstract
An unprecedented cheap, mild and easy methodology for an intramolecular Minisci reaction based on a hydrogen atom transfer (HAT) initiated hydrofunctionalization of olefins was developed. The method is suitable for the construction of unusual dihydropyrano-pyridine and 1,2,3,4-tetrahydronaphthiridine structures and, unlike most similar reactions, does not require exclusion of air from the reaction medium.
摘要
开发了一种前所未有的基于氢原子转移 (HAT) 引发的烯烃氢官能化的分子内 Minisci 反应的廉价、温和、简便的方法。该方法适用于不常见的二氢吡喃并吡啶和 1,2,3,4-四氢萘啶结构的构建，与大多数类似反应不同，它不需要从反应介质中排除空气。
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