一种基于具有三个5-碘-1,2,3-三唑亚基的假环肽的中性卤素键合大环阴离子受体。
A neutral halogen bonding macrocyclic anion receptor based on a pseudocyclopeptide with three 5-iodo-1,2,3-triazole subunits.
作者信息
Mungalpara Disha, Stegmüller Simone, Kubik Stefan
机构信息
Technische Universität Kaiserslautern, Fachbereich Chemie - Organische Chemie, Erwin-Schrödinger-Straße, 67663, Kaiserslautern, Germany.
出版信息
Chem Commun (Camb). 2017 May 4;53(37):5095-5098. doi: 10.1039/c7cc02424j.
PMID:28443873
Abstract
The converging arrangement of iodine atoms along its confined cavity causes a cyclic pseudopeptide with three 5-iodo-1,2,3-triazole subunits to interact with halides, in particular with chloride, in 2.5 vol% water/DMSO.
摘要
碘原子沿其受限腔的汇聚排列使得具有三个5-碘-1,2,3-三唑亚基的环状假肽在2.5体积%的水/二甲亚砜中与卤化物，特别是与氯化物相互作用。
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