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本文引用的文献

1
Aqueous biphasic systems composed of ionic liquids and polypropylene glycol: insights into their liquid-liquid demixing mechanisms.由离子液体和聚丙二醇组成的双水相体系:对其液-液分层机制的深入了解
Phys Chem Chem Phys. 2016 Jul 27;18(30):20571-20582. doi: 10.1039/c6cp04023c.
2
Thermoreversible (Ionic-Liquid-Based) Aqueous Biphasic Systems.热可逆(基于离子液体的)双水相体系
Sci Rep. 2016 Feb 4;6:20276. doi: 10.1038/srep20276.
3
Impact of pH and temperature on phase diagrams of different aqueous biphasic systems.pH值和温度对不同双水相体系相图的影响。
J Chromatogr A. 2016 Feb 12;1433:41-55. doi: 10.1016/j.chroma.2016.01.016. Epub 2016 Jan 12.
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Dual Ionic and Organic Nature of Ionic Liquids.离子液体的双离子与有机特性
Sci Rep. 2016 Jan 19;6:19644. doi: 10.1038/srep19644.
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Controlling the Formation of Ionic-Liquid-based Aqueous Biphasic Systems by Changing the Hydrogen-Bonding Ability of Polyethylene Glycol End Groups.通过改变聚乙二醇端基的氢键能力来控制离子液体基双水相体系的形成
Chemphyschem. 2015 Jul 20;16(10):2219-25. doi: 10.1002/cphc.201500146. Epub 2015 May 5.
6
Molecular interactions in aqueous biphasic systems composed of polyethylene glycol and crystalline vs. liquid cholinium-based salts.由聚乙二醇与结晶型和液态胆碱盐组成的双水相体系中的分子相互作用。
Phys Chem Chem Phys. 2014 Mar 28;16(12):5723-31. doi: 10.1039/c3cp54907k. Epub 2014 Feb 13.
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"Washing-out" ionic liquids from polyethylene glycol to form aqueous biphasic systems.将离子液体从聚乙二醇中“洗出”以形成双水相体系。
Phys Chem Chem Phys. 2014 Feb 14;16(6):2271-4. doi: 10.1039/c3cp54047b.
8
Inorganic salts in purely ionic liquid media: the development of High Ionicity Ionic Liquids (HIILs).在纯离子液体介质中的无机盐:高离子强度离子液体(HIILs)的发展。
Chem Commun (Camb). 2012 Apr 14;48(30):3656-8. doi: 10.1039/c2cc30374d. Epub 2012 Mar 6.
9
Insight into the interactions that control the phase behaviour of new aqueous biphasic systems composed of polyethylene glycol polymers and ionic liquids.深入了解控制由聚乙二醇聚合物和离子液体组成的新双水相系统的相行为的相互作用。
Chemistry. 2012 Feb 6;18(6):1831-9. doi: 10.1002/chem.201101780. Epub 2012 Jan 3.
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Ionic liquids: just Molten salts after all?离子液体:终究只是熔盐而已?
Molecules. 2009 Jul 13;14(7):2521-34. doi: 10.3390/molecules14072521.

双水相体系的温度依赖性:一种探索库仑主导盐与离子液体之间差异的替代方法。

Temperature dependency of aqueous biphasic systems: an alternative approach for exploring the differences between Coulombic-dominated salts and ionic liquids.

作者信息

E Silva Francisca A, Pereira Jorge F B, Kurnia Kiki A, Ventura Sónia P M, Silva Artur M S, Rogers Robin D, Coutinho João A P, Freire Mara G

机构信息

CICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.

出版信息

Chem Commun (Camb). 2017 Jul 7;53(53):7298-7301. doi: 10.1039/c7cc02294h. Epub 2017 Apr 27.

DOI:10.1039/c7cc02294h
PMID:28447082
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6157718/
Abstract

Herein we propose an alternative way to distinguish ionic liquids from Coulombic-dominated salts, based not on their upper limit melting temperature (100 °C), but on the trend of their phase-forming abilities to create aqueous biphasic systems as a function of temperature, in which a wider plethora of interactions can be appraised.

摘要

在此,我们提出一种区分离子液体与以库仑力为主导的盐的替代方法,该方法不是基于它们的上限熔点温度(100℃),而是基于它们形成水相双相系统的相形成能力随温度变化的趋势,在这种系统中可以评估更多种类的相互作用。