Chemistry, University of Southampton, University Road, Southampton, SO17 1BJ, UK.
Chem Soc Rev. 2017 May 9;46(9):2577-2591. doi: 10.1039/c7cs00199a.
The use of metal ions to template the synthesis of catenanes by Sauvage and co-workers was a pivotal moment in the development of the field of interlocked molecules. In this Review Article we shall examine the different roles metal-ligand interactions play in modern syntheses of interlocked molecules and materials, with a particular focus on seminal contributions and the advantages and disadvantages of employing metal ligand interactions.
Sauvage 及其同事使用金属离子作为模板合成索烃,这是分子互锁领域发展的一个关键时刻。在这篇综述文章中,我们将研究金属-配体相互作用在现代分子互锁和材料合成中的不同作用,特别关注开创性的贡献以及利用金属配体相互作用的优缺点。