Gupta Vinod Kumar, Fakhri Ali, Agarwal Shilpi, Sadeghi Nima
Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa.
Young Researchers and Elites Club, Science and Research Branch, Islamic Azad University, Tehran, Iran; Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran.
Int J Biol Macromol. 2017 Sep;102:840-846. doi: 10.1016/j.ijbiomac.2017.04.075. Epub 2017 Apr 24.
The MnO/Cellulose fiber Nanocomposites have been prepared via the microwave-assisted hydrothermal method. The characteristic structure of MnO/Cellulose fiber Nanocomposites was analyzed using X-ray diffraction, photoluminescence and UV-vis spectra, Transmission electron Microscopy, N adsorption-desorption and Scanning electron microscopy instrumental techniques. BET surface area and crystallite size values of MnO/cellulose fiber nanocomposites have been found as 87.064m/g and 70.0nm, respectively. Response Surface Methodology (RSM) has been used for adsorption of Insecticide compound such as Toxaphene by prepared adsorbent. MnO/Cellulose fiber Nanocomposites shows maximum removal of 96.5% at initial Toxaphene concentration of 5.0mg/L, pH 3 and adsorbent dose of 5.0g/L. Kinetic and equilibrium data follow pseudo-second order and Langmuir isotherm model, respectively. Adsorption capacity of MnO/Cellulose fiber Nanocomposites has been found to be 5.465mg/g.
通过微波辅助水热法制备了MnO/纤维素纤维纳米复合材料。利用X射线衍射、光致发光和紫外可见光谱、透射电子显微镜、N吸附-脱附和扫描电子显微镜等仪器技术对MnO/纤维素纤维纳米复合材料的特征结构进行了分析。发现MnO/纤维素纤维纳米复合材料的BET表面积和微晶尺寸值分别为87.064m/g和70.0nm。响应面法（RSM）已用于所制备的吸附剂对杀虫剂化合物毒杀芬的吸附。MnO/纤维素纤维纳米复合材料在初始毒杀芬浓度为5.0mg/L、pH值为3、吸附剂剂量为5.0g/L时，最大去除率为96.5%。动力学和平衡数据分别遵循准二级和朗缪尔等温线模型。发现MnO/纤维素纤维纳米复合材料的吸附容量为5.465mg/g。
