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作为用于全水分裂的高效双功能电催化剂的钴镍硒化物

CoNiSe as an efficient bifunctional electrocatalyst for overall water splitting.

作者信息

Amin Bahareh Golrokh, Swesi Abdurazag T, Masud Jahangir, Nath Manashi

机构信息

Department of Chemistry, Missouri University of Science & Technology, Rolla, MO 65409, USA.

出版信息

Chem Commun (Camb). 2017 May 11;53(39):5412-5415. doi: 10.1039/c7cc01489a.

DOI:10.1039/c7cc01489a
PMID:28451675
Abstract

CoNiSe with a vacancy-ordered spinel structure shows excellent bifunctional electrocatalytic activity for water splitting in alkaline medium producing 10 mA cm at a cell voltage of 1.61 V. For OER, an overpotential of 160 mV was needed for 10 mA cm which is one of the lowest overpotentials reported to date.

摘要

具有空位有序尖晶石结构的CoNiSe在碱性介质中对水分解表现出优异的双功能电催化活性,在电池电压为1.61 V时产生10 mA cm 。对于析氧反应(OER),在10 mA cm 时需要160 mV的过电位,这是迄今为止报道的最低过电位之一。

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