Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6272; email:
Annu Rev Chem Biomol Eng. 2017 Jun 7;8:499-523. doi: 10.1146/annurev-chembioeng-060816-101531. Epub 2017 Apr 26.
In this review we summarize recent efforts in understanding nano-aggregation in acid- and ion-containing polymer systems. The acid and ionic groups have specific interactions that drive aggregation and alter polymer behavior at the nano-, micro-, and bulk length scales. Advancements in synthetic methods, characterization techniques, and computer simulations have enabled researchers to better understand the morphologies and dynamics, particularly at the nanoscale. This overview of recent advancements in nano-aggregated polymer systems highlights the current understanding of the field and presents promising directions for future investigations and new applications.
在这篇综述中,我们总结了近年来人们在理解含酸和离子的聚合物系统中的纳米聚集方面的努力。酸和离子基团具有特定的相互作用,这些相互作用驱动了聚集,并在纳米、微米和体相长度尺度上改变了聚合物的行为。合成方法、表征技术和计算机模拟的进步使研究人员能够更好地理解形态和动力学,特别是在纳米尺度上。本综述介绍了近期纳米聚集聚合物系统的进展,强调了该领域的现有认识,并提出了未来研究和新应用的有前景的方向。