Kumar Amrit, Hua Carol, Madden David G, O'Nolan Daniel, Chen Kai-Jie, Keane Lee-Ann J, Perry John J, Zaworotko Michael J
Bernal Institute, Department of Chemical Sciences, University of Limerick, Limerick, Republic of Ireland.
Chem Commun (Camb). 2017 May 30;53(44):5946-5949. doi: 10.1039/c7cc02289a.
Fine-tuning of HUMs through pillar substitution can significantly enhance trace CO sorption performance and stability. The resulting materials, exemplified by the new material TIFSIX-3-Ni, [Ni(pyrazine)(TiF)], are shown through temperature programmed desorption experiments to remove trace quantities of CO from moist gas mixtures.
通过柱体取代对金属有机材料（HUMs）进行微调可以显著提高痕量CO的吸附性能和稳定性。以新材料TIFSIX-3-Ni，即[Ni（吡嗪）（TiF）]为例，通过程序升温脱附实验表明，所得材料能够从潮湿气体混合物中去除痕量的CO。
