通过机械化学法绿色快速合成锆基金属有机框架：在一百秒内获得UiO-66类似物纳米晶体。
Green and rapid synthesis of zirconium metal-organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds.
作者信息
Huang Yi-Hao, Lo Wei-Shang, Kuo Yun-Wei, Chen Wen-Jin, Lin Chia-Her, Shieh Fa-Kuen
机构信息
Department of Chemistry, National Central University, 300 Chung-Da Road, Chung Li, 32001, Taiwan.
出版信息
Chem Commun (Camb). 2017 May 30;53(43):5818-5821. doi: 10.1039/c7cc03105j.
A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.
采用水辅助研磨法在100秒内合成了一种UiO-66类似物。连接体的溶解性表明四氟苯-1,4-二甲酸是最佳连接体。锆基金属有机框架纳米晶体表现出良好的拓扑结构和疏水性，以及较高的水稳定性和热稳定性。较少的无定形络合物在研磨60分钟时导致更高的孔隙率和孔体积。
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