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一种生物医用Ti-25Nb-3Mo-3Zr-2Sn合金在林格氏液中的摩擦腐蚀行为。

Tribocorrosion behaviour of a biomedical Ti-25Nb-3Mo-3Zr-2Sn alloy in Ringer's solution.

作者信息

Wang Zhenguo, Huang Weijiu, Li Yan, He Haoran, Zhou Yongtao, Zheng Ziqing

机构信息

School of Materials Science and Engineering, Beihang University, Beijing 100191, China; Beijing Key Laboratory for Advanced Functional Materials and Thin Film Technology, Beihang University, Beijing 100191, China.

School of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, China.

出版信息

Mater Sci Eng C Mater Biol Appl. 2017 Jul 1;76:1094-1102. doi: 10.1016/j.msec.2017.03.206. Epub 2017 Mar 23.

Abstract

The tribocorrosion behaviour of biomaterial Ti-25Nb-3Mo-3Zr-2Sn alloy in Ringer's solution was evaluated by micro-abrasion experiments, electrochemical tests and scanning electron microscope (SEM) observations. Potentiodynamic polarization results suggested that the effect of particle concentration on the electrochemistry characteristic is greater than the applied load. When the particle concentration and applied load were 0.05g·cm and 0.25N, respectively, the E reached the maximum as -0.381V. The micro-abrasion-corrosion results showed that the wear rates of the Ti-25Nb-3Mo-3Zr-2Sn alloy increased with increasing particle concentration and decreased as applied load increased. The wear rates acquired under various conditions regarding to the main wear mechanism of two-body grooving wear with less three-body rolling wear; three-body abrasive wear modes are more efficient at material loss than two-body wear. The variation in material loss indicated that the contribution of corrosion is lower than the contribution of micro-abrasion. The wear regime, wastage and micro-abrasion-corrosion synergy maps associated with the particle concentration and applied load were established to evaluate the tribocorrosion behaviour of the Ti-25Nb-3Mo-3Zr-2Sn alloy as a potential surgical implant material.

摘要

通过微磨损实验、电化学测试和扫描电子显微镜(SEM)观察,评估了生物材料Ti-25Nb-3Mo-3Zr-2Sn合金在林格氏溶液中的摩擦腐蚀行为。动电位极化结果表明,颗粒浓度对电化学特性的影响大于外加负载。当颗粒浓度和外加负载分别为0.05g·cm和0.25N时,E达到最大值-0.381V。微磨损腐蚀结果表明,Ti-25Nb-3Mo-3Zr-2Sn合金的磨损率随颗粒浓度增加而增大,随外加负载增加而减小。在各种条件下获得的磨损率主要归因于两体沟槽磨损机制,三体滚动磨损较少;三体磨料磨损模式在材料损失方面比两体磨损更有效。材料损失的变化表明腐蚀的贡献低于微磨损的贡献。建立了与颗粒浓度和外加负载相关的磨损状态、损耗和微磨损腐蚀协同作用图,以评估Ti-25Nb-3Mo-3Zr-2Sn合金作为潜在外科植入材料的摩擦腐蚀行为。

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