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用于形成高度有序自组装单分子层的结合基团:羧基与硫醇基。

Binding groups for highly ordered SAM formation: carboxylic versus thiol.

作者信息

Krzykawska A, Ossowski J, Żaba T, Cyganik P

机构信息

Smoluchowski Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków, Poland.

出版信息

Chem Commun (Camb). 2017 May 23;53(42):5748-5751. doi: 10.1039/c7cc01939d.

DOI:10.1039/c7cc01939d
PMID:28492691
Abstract

The structure of analogous SAMs chemisorbed on an Ag substrate via a -SH or -COOH binding group is reported. Our observations indicate that COOH binding groups can be considered as a promising alternative for the current standard based on the sulfur binding groups, particularly when 2D ordering, SAM fabrication time and stability under ambient conditions are of great importance.

摘要

报道了通过-SH或-COOH结合基团化学吸附在银基底上的类似自组装单分子膜(SAMs)的结构。我们的观察结果表明,基于硫结合基团的当前标准,COOH结合基团可被视为一种有前景的替代方案,特别是当二维有序性、SAM制备时间和在环境条件下的稳定性非常重要时。

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