Seitz Andreas E, Vogel Ulf, Eberl Miriam, Eckhardt Maria, Balázs Gábor, Peresypkina Eugenia V, Bodensteiner Michael, Zabel Manfred, Scheer Manfred
Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93040, Regensburg, Germany.
Nikolaev Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentiev str. 3, 630090, Novosibirsk, Russia.
Chemistry. 2017 Aug 1;23(43):10319-10327. doi: 10.1002/chem.201701380. Epub 2017 Jun 23.
A detailed method for the preparation of [Cp'' Zr(η -P )] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe , AlEt ) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis.
本文介绍了一种制备[Cp''Zr(η -P )] (1)的详细方法。通过计算和实验研究，详细考察了1分别与钨、锰和铁的路易斯酸性过渡金属配合物以及主族化合物（AlMe 、AlEt ）的配位行为。在此过程中，合成了一系列具有不同配位模式和四磷双环[1.1.0]丁烷骨架多配位数的前所未有的配合物。所有产物以及起始原料均通过核磁共振光谱、质谱、元素分析和单晶X射线结构分析进行了全面表征。
