Mandizadeh Samira, Soofivand Faezeh, Bagheri Samira, Salavati-Niasari Masoud
Institute of Nano Science and Nano Technology, University of Kashan, Kashan, I. R. Iran.
Nanotechnology & Catalysis Research Centre (NANOCAT), IPS Building, University of Malaya, Kuala Lumpur, Malaysia.
PLoS One. 2017 May 11;12(5):e0162891. doi: 10.1371/journal.pone.0162891. eCollection 2017.
In this work, SrCrxFe12-xO19 (x = 0.0, 0.5, 1.0, 1.5) nanostructures were successfully synthesized by sol-gel auto-combustion method, and different aminoacids were used as green reductants. Various analysis results show that SrCrxFe12-xO19 nanoparticles synthesized successfully.The present study shows that SrCrxFe12-xO19 nanoparticle could be used as adsorbent for the desulfurization of liquid fuels. Increasing of nanoparticles concentration was caused to increase the adsorption rate of sulfur contents of fuel. The adsorption rate of sulfur contents of fuel in various concentrations 4.5, 9.5, and 18.5 g. L -1 of SrCrxFe12-xO19 nanoparticles in solution was estimated about 39, 50, and 62% for 30 min, respectively. The results of catalytic tests reveals that SrCrxFe12-xO19 nanoparticles have the potential to be used as a new kind of semiconductor catalysts for the desulfurization of liquid fuels. Magnetic property of the final sample was measured at room temperature by a vibration sample magnetometer (VSM) and shown that the intrinsic coercivity of product is about 6000 Oe and it exhibits characteristics of single magnetic domains (Mr/ Ms = 0.53).
在本工作中,通过溶胶 - 凝胶自燃烧法成功合成了SrCrxFe12 - xO19(x = 0.0、0.5、1.0、1.5)纳米结构,并使用了不同的氨基酸作为绿色还原剂。各种分析结果表明成功合成了SrCrxFe12 - xO19纳米颗粒。本研究表明,SrCrxFe12 - xO19纳米颗粒可作为液体燃料脱硫的吸附剂。纳米颗粒浓度的增加导致燃料中硫含量的吸附率提高。在溶液中SrCrxFe12 - xO19纳米颗粒浓度分别为4.5、9.5和18.5 g·L -1时,燃料中硫含量在30分钟内的吸附率分别约为39%、50%和62%。催化测试结果表明,SrCrxFe12 - xO19纳米颗粒有潜力用作液体燃料脱硫的新型半导体催化剂。通过振动样品磁强计(VSM)在室温下测量了最终样品的磁性,结果表明产物的内禀矫顽力约为6000 Oe,并且它表现出单磁畴的特性(Mr / Ms = 0.53)。